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Citation: Qi Shuzhen, Gao Xueqin, Xiao Shuhui, Chen Wenqi. SYNTHESIS OF BENZENE-NEODYMIUM COMPLEX AND ITS CATALYTIC ACTIVITY ON THE POLYMERIZATION OF BUTADIENE[J]. Chinese Journal of Applied Chemistry, ;1986, 3(1): 63-65. shu

SYNTHESIS OF BENZENE-NEODYMIUM COMPLEX AND ITS CATALYTIC ACTIVITY ON THE POLYMERIZATION OF BUTADIENE

1.
Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 17 January 1985
Available Online: 3 April 1985

In this paper the reaction of Nd metal vapor produced at high temperature below 10^-5 mmHg with bezene at -196℃ to give benzeneneodymium complex has been investigated. The chemical composition of the product was identified as (C₆H₆)₃Nd₂ by chemical analysis. The product is a black needle solid, insoluble in organic solvents, stable at room temperature, extremely sensitive to air and moisture and pyrophoric in air. The complex decomposes by water and alcohol, evolving hydrogen. Combined with Al₂Et₃Cl₃ the complex polymerizes butadiene to polymer with cis-1,4 content of 77.3%, trans-1,4 17.4%, and 1,2 5.3%.
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