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Citation: Sun Tao, Yang Jihua, Pang Shufen, Ouyang Jun. THE KINETICS OF POLYMERIZATION OF BUTADIENE WITH Nd(OCt)₃-HAI(i-Bu)₂-CH₂=CHCH₂CI SYSTEM[J]. Chinese Journal of Applied Chemistry, ;1985, 2(2): 47-51. shu

THE KINETICS OF POLYMERIZATION OF BUTADIENE WITH Nd(OCt)₃-HAI(i-Bu)₂-CH₂=CHCH₂CI SYSTEM

1.
Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 17 September 1984
Available Online: 19 December 1984
Fund Project:

The kinetics of butadiene polymerization with a soluble rare earth catalyst(Nd(OCt)₃-HAl(i-Bu)₂-CH₂=CHCH₂Cl) has been studied. The experimental results showed that the rate of polymerization is first order in both the concentrations of monomer and neodymium compound, but is 1/3 order in the concentration of diisobutyl aluminum hydride. The number of active center and the apparent activation energy and the propagation activation energy of butadiene polymerization were determined.
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THE KINETICS OF POLYMERIZATION OF BUTADIENE WITH Nd(OCt)3-HAI(i-Bu)2-CH2=CHCH2CI SYSTEM

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THE KINETICS OF POLYMERIZATION OF BUTADIENE WITH Nd(OCt)₃-HAI(i-Bu)₂-CH₂=CHCH₂CI SYSTEM