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Citation: Wu Shengde, Luo Fucheng, Teng Youwei, Li Guangnian. SYNTHESIS OF COBALT PORPHYRINS AND THEIR COORDINATION CATALYTIC ACTIVITY[J]. Chinese Journal of Applied Chemistry, ;1985, 2(2): 43-46. shu

SYNTHESIS OF COBALT PORPHYRINS AND THEIR COORDINATION CATALYTIC ACTIVITY

1.
Chengdu Institute of Organic Chemistry, Academia Sinica

Received Date: 15 October 1984
Available Online: 23 January 1985

Nine cobalt 5, 15-di(p-substituted phenyl) cctaalkyl porphyrins were synthesized and the effect of para-phenyl substituents on coordination reaction of porphyrins with cobalt salt was studied. It has been shown that the reaction follows the rate expression: -dH₂P/dt=K_obh[H₂P] and the reaction rate is influenced by substituents: H >CH₃ >OCH₃ >N <_CH₃^CH₃, corresponding to the Hammett relationship. The experimental results shown that the presence of electron-donating substituent improvs the catalytic activity of title compound in hydroquinone oxidation reaction.
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