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Citation: Wang Yihui. THE CHEMICAL FORMS AND LASER PROPERTIES OF Nd³⁺ ION IN SOME INORGANIC SOLVENTS[J]. Chinese Journal of Applied Chemistry, ;1985, 2(1): 54-59. shu

THE CHEMICAL FORMS AND LASER PROPERTIES OF Nd³⁺ ION IN SOME INORGANIC SOLVENTS

Wang Yihui

1.
Changchun Institute of Applied chemistry, Academia Sinica

Received Date: 12 March 1984
Available Online: 13 September 1984

Some liguid laser solutions containing Nd³⁺ ion were prepared in inorganic solvents. It was found that the composition and proportion of the solvents in the solution reveal an influence on the viscosity, lifetime of ⁴F_3/2 energy level for Nd³⁺ ion and output of laser energy.The high stability of the Nd³⁺ complex and the long lifetime of the energy level for Nd³⁺ ion are considered to be caused by three factors:the first coordinated sphere for Nd³⁺ ion is occupied by oxygen atoms, the solvation of the Nd³⁺-containing complexes with POCl₃ molecules and the formation of P=O→SnCl₄ (donor acceptor) bonding.
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THE CHEMICAL FORMS AND LASER PROPERTIES OF Nd³⁺ ION IN SOME INORGANIC SOLVENTS