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Citation: Jin Shixiong, Tian Rujiang. STUDY ON THE ANODIC REACTION OF OXYGEN EVOLUTION Ⅰ. THE KINETICS OF OXYGEN EVOLUTION ON AND MILD STEEL IN BASE[J]. Chinese Journal of Applied Chemistry, ;1985, 2(1): 39-42. shu

STUDY ON THE ANODIC REACTION OF OXYGEN EVOLUTION Ⅰ. THE KINETICS OF OXYGEN EVOLUTION ON AND MILD STEEL IN BASE

1.
Department of Chemistry, Nankai University

Received Date: 27 April 1984
Available Online: 6 October 1984

The kinetics of O₂ anodic evolution was studied in alk.solution. The results show that the values of ∂ψ/∂lgi egual 39 mV and 120 mV at low andhigh currents, respectively, and that of ∂ψ/∂lga_OH^- egual -2×39 mV at low currents and-120 mV at high currents. The kinetic data obtained show that the rate determining step of the anodic evolution of oxygen on Pt and mild steel electrode is MOH_ad+OH^-→MO_ad+H₂O+e The influences of Li⁺, Na⁺, K⁺, CNS^- and Cl^- ions on the reaction ratewere discussed as well.
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