Citation: Chen Yiyong, Mao Weihong, Wang Naidong. ADSORPTION AND ADSORPTION MECHANISM OF 4-AMINO-1,2,4-TRIAZOLE RESIN FOR Cr(VI)[J]. Chinese Journal of Applied Chemistry, ;1992, 9(6): 31-35. shu

ADSORPTION AND ADSORPTION MECHANISM OF 4-AMINO-1,2,4-TRIAZOLE RESIN FOR Cr(VI)

1.
Department of Chemistry, Hangzhou University, Hangzhou 310028

Received Date: 19 December 1991
Available Online: 25 March 1992

Cr(Ⅵ) was quantitatively adsorbed by 4-amino-1,2,4-triazole resin(4-ATR) in a medium of pH=1,but Cr³⁺ almost could not be adsorbed. The separation coefficient β_{Cr(Ⅵ)/Cr³⁺} is as high as 5.52×10³. The statically saturated sorption capacity is 179.4mg Cr(Ⅵ)/gresin[3.45 mmol Cr(Ⅵ)/g resin]. Cr(Ⅵ) adsorbed on 4-ATR can be reductively eluated by 5mol/L HCL. The sorption rate constants determined under various temperatures were k_21℃=1.59×1O^-3S^-1,k_25℃=1.87×10^-3S^-1 and k_30℃=2.2×10^-3S^-1,respectively. The apparent activation energy of sorption E₂ is 26.26kJ/mol.The thermodynamic parameters of sorption,enthalpy ΔH₂₉₈,freeenergy ΔG₂₉₈,and entropy ΔS₂₉₈ of sorption (4-ATR) for Cr(Ⅵ) are 86.16, -15.1 kJ/mol,and 339.8 J/mol·Κ,respectively.Coordination molar ratio of Cr(Ⅵ)to -NH-H???19920607??? is 1:1. The sorption mechanism shows that the nitrogen atoms of the functional group of 4-ATR coordinated with Cr(Ⅵ) to form coordination bond. The 4-ATR can be used in the separation of Cr(Ⅵ) from the waste electroplating water. The percentage of recovery of chromium is 95.7.%., Cr(Ⅵ) was quantitatively adsorbed by 4-amino-1,2,4-triazole resin(4-ATR) in a medium of pH=1,but Cr³⁺ almost could not be adsorbed. The separation coefficient β_{Cr(Ⅵ)/Cr³⁺} is as high as 5.52×10³. The statically saturated sorption capacity is 179.4mg Cr(Ⅵ)/gresin[3.45 mmol Cr(Ⅵ)/g resin]. Cr(Ⅵ) adsorbed on 4-ATR can be reductively eluated by 5mol/L HCL. The sorption rate constants determined under various temperatures were k_21℃=1.59×1O^-3S^-1,k_25℃=1.87×10^-3S^-1 and k_30℃=2.2×10^-3S^-1,respectively. The apparent activation energy of sorption E₂ is 26.26kJ/mol.The thermodynamic parameters of sorption,enthalpy ΔH₂₉₈,freeenergy ΔG₂₉₈,and entropy ΔS₂₉₈ of sorption (4-ATR) for Cr(Ⅵ) are 86.16, -15.1 kJ/mol,and 339.8 J/mol·Κ,respectively.Coordination molar ratio of Cr(Ⅵ)to -NH-H3+ almost could not be adsorbed. The separation coefficient β_{Cr(Ⅵ)/Cr³⁺} is as high as 5.52×10³. The statically saturated sorption capacity is 179.4mg Cr(Ⅵ)/gresin[3.45 mmol Cr(Ⅵ)/g resin]. Cr(Ⅵ) adsorbed on 4-ATR can be reductively eluated by 5mol/L HCL. The sorption rate constants determined under various temperatures were k_21℃=1.59×1O^-3S^-1,k_25℃=1.87×10^-3S^-1 and k_30℃=2.2×10^-3S^-1,respectively. The apparent activation energy of sorption E₂ is 26.26kJ/mol.The thermodynamic parameters of sorption,enthalpy ΔH₂₉₈,freeenergy ΔG₂₉₈,and entropy ΔS₂₉₈ of sorption (4-ATR) for Cr(Ⅵ) are 86.16, -15.1 kJ/mol,and 339.8 J/mol·Κ,respectively.Coordination molar ratio of Cr(Ⅵ)to -NH-H is 1:1. The sorption mechanism shows that the nitrogen atoms of the functional group of 4-ATR coordinated with Cr(Ⅵ) to form coordination bond. The 4-ATR can be used in the separation of Cr(Ⅵ) from the waste electroplating water. The percentage of recovery of chromium is 95.7.%., Cr(Ⅵ) was quantitatively adsorbed by 4-amino-1,2,4-triazole resin(4-ATR) in a medium of pH=1,but Cr³⁺ almost could not be adsorbed. The separation coefficient β_{Cr(Ⅵ)/Cr³⁺} is as high as 5.52×10³. The statically saturated sorption capacity is 179.4mg Cr(Ⅵ)/gresin[3.45 mmol Cr(Ⅵ)/g resin]. Cr(Ⅵ) adsorbed on 4-ATR can be reductively eluated by 5mol/L HCL. The sorption rate constants determined under various temperatures were k_21℃=1.59×1O^-3S^-1,k_25℃=1.87×10^-3S^-1 and k_30℃=2.2×10^-3S^-1,respectively. The apparent activation energy of sorption E₂ is 26.26kJ/mol.The thermodynamic parameters of sorption,enthalpy ΔH₂₉₈,freeenergy ΔG₂₉₈,and entropy ΔS₂₉₈ of sorption (4-ATR) for Cr(Ⅵ) are 86.16, -15.1 kJ/mol,and 339.8 J/mol·Κ,respectively.Coordination molar ratio of Cr(Ⅵ)to -NH-H is 1:1. The sorption mechanism shows that the nitrogen atoms of the functional group of 4-ATR coordinated with Cr(Ⅵ) to form coordination bond. The 4-ATR can be used in the separation of Cr(Ⅵ) from the waste electroplating water. The percentage of recovery of chromium is 95.7.%.
- aminotriazole,
- chromium ion,
- adsorption
1. [1]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . 微观结构调控的g-C₃N₄在光催化NO转化中的最新进展：吸附/活化位点的关键作用. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-. doi: 10.1016/j.actphy.2024.100039
2. [2]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
3. [3]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
4. [4]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
5. [5]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
6. [6]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
7. [7]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
8. [8]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
9. [9]
  Linhan Tian , Changsheng Lu . Discussion on Sextuple Bonding in Diatomic Motifs of Chromium Family Elements. University Chemistry, 2024, 39(8): 395-402. doi: 10.3866/PKU.DXHX202401056
10. [10]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
11. [11]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
12. [12]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
13. [13]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
14. [14]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
15. [15]
  Yongqing Kuang , Jie Liu , Jianjun Feng , Wen Yang , Shuanglian Cai , Ling Shi . Experimental Design for the Two-Step Synthesis of Paracetamol from 4-Hydroxyacetophenone. University Chemistry, 2024, 39(8): 331-337. doi: 10.12461/PKU.DXHX202403012
16. [16]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
17. [17]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
18. [18]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
19. [19]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
20. [20]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(242)
HTML views(19)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142