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Citation: Chen Yuanyin, Lu Xueran, Fang Guoqing. POLYSILOXANE-SUPPORTED SULFIDE-AMINE-PLATINUM COMPLEX: SYNTHESIS AND ITS CATALYTIC ACTIVITY IN HYDROSILYLATION OF OLEFINS[J]. Chinese Journal of Applied Chemistry, ;1992, 9(4): 26-30. shu

POLYSILOXANE-SUPPORTED SULFIDE-AMINE-PLATINUM COMPLEX: SYNTHESIS AND ITS CATALYTIC ACTIVITY IN HYDROSILYLATION OF OLEFINS

1.
Department of Chemistry, Wuhan University, Wuhan 430072

Corresponding author: Chen Yuanyin,
Received Date: 31 January 1991
Available Online: 2 July 1991
Fund Project:

4-Thia-6-dimethylaminohexyltrimethoxysilane was synthesized by condensation of γ-mereaptopropyltrimethoxysilane and β-chloroethyldimethylamine hydrochloride in the presence of sodium methoxide. The new silicon monomer was subjected to hydrolysis and immobilization on fumed silica, followed by reaction with potassium chloroplatinite to give the title platinum complex. The complex was found to be an effective catalyst for the hydrosilylation of olefins with triethoxysilane.The influences of temperature, the amount of the complex used,and the kind of olefins on the catalytic activity were investigated.
- supported-catalyst,
- hydrosilylation,
- sulfide,
- amine-containing silicon monomer
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