Citation:
Wen Ke, Cao Xizhang. SYNTHESES OF AMPHIPHILIC PORPHYRINS AND THEIR LANGMUIR-BLODGETT FILMS[J]. Chinese Journal of Applied Chemistry,
;1992, 9(3): 70-71.
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Tetra-(N,N-dimethylaminophenyl)porphyrin(TDMAPP) reacts with n-C16H33Br to give quaternary bromides of the amphiphilie porphyrin containing four long aliphatic chains. Its Cu, Zn and Co complexes have been prepared. These porphyrins are capable of forming Langmuir-Blodgett films. The UV-Visible spectra of the L-B films as well as of the solid compounds indicate that the interations between molecules in two cases are different.
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Keywords:
- long chain porphyrin derivative,
- synthesis,
- L-B film
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