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Citation: Song Shuzhong, Yu Junxue, Xi Zuwei. HETEROGENEOUS CATALYTIC HYDROGENATION OF 4,5-EPOXY-2-PENTENAL[J]. Chinese Journal of Applied Chemistry, ;1992, 9(3): 11-14. shu

HETEROGENEOUS CATALYTIC HYDROGENATION OF 4,5-EPOXY-2-PENTENAL

1.
Dalian Institute of Chemical Physics, Academia Sinica, Dalian 116012

Corresponding author: Song Shuzhong,
Received Date: 31 January 1991
Available Online: 17 May 1991

The catalytic hydrogenation of 4,5-epoxy-2-pentenal on Pd and Ni catalysts has been studied.For Pd catalyst the products obtained were 4,5-epoxypentanal (1) and 2-hydroxytetrahydropyran (2), and for Ni catalyst they were (2) and 1,5-pentadiol (3).The maximum yield of 1,2 and 3 is 58.8%, 62.0% and 84.7%, respectively. The influences of various catalysts on the composition of hydrogenation products were discussed.
- catalytic hydrogenation,
- epoxypentenal,
- pentadiol,
- nickel catalyst,
- palladium catalyst
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