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Citation: Zhuang Jia, Cheng Quan, Xin Xinquan, Zheng Limin. SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅩⅩⅢ. THE SOLID STATE SUBSTITUTION REACTION OF (Co(NH₃)₄CO₃)Cl and (Co(en)₂CO₃)Cl WITH NH₄SCN[J]. Chinese Journal of Applied Chemistry, ;1992, 9(2): 33-37. shu

SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅩⅩⅢ. THE SOLID STATE SUBSTITUTION REACTION OF (Co(NH₃)₄CO₃)Cl and (Co(en)₂CO₃)Cl WITH NH₄SCN

1.
Department of Chemistry, Nanjing University, Nanjing 210008

Corresponding author: Xin Xinquan,
Received Date: 8 April 1991
Available Online: 26 June 1991
Fund Project:

Solid state substitution reactions take place between (Co(NH₃)₄CO₃)Cl or (Co(en)₂CO₃)Cl with NH₄SCN at 100℃, with the non-volatized CO₃^2- being substituted outside the inner coordination sphcrc by SCN^-. Trans-(Co(NH₃)₄(NCS)₂)Cl is formed in the reaction of (Co(NH₃)₄CO₃)Cl with NH₄SCN. However, in the reaction bctwccn(Co(en)₂CO₃)Cl and NH₄SCN, Cis-Co(en)₂(NCS)₂Cl is at first formed transforming into trans-isomer ultimately. Two reactions are believed to proceed through S_N² mechanism.
- solid state reaction,
- substitution,
- (Co(NH₃)₄CO₃)Cl,
- (Co(en)₂CO₃)Cl
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SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅩⅩⅢ. THE SOLID STATE SUBSTITUTION REACTION OF (Co(NH3)4CO3)Cl and (Co(en)2CO3)Cl WITH NH4SCN

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SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅩⅩⅢ. THE SOLID STATE SUBSTITUTION REACTION OF (Co(NH₃)₄CO₃)Cl and (Co(en)₂CO₃)Cl WITH NH₄SCN