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Citation: Lin Yanan, Zhang Chongrong, Dong Wenhao, Zhang Shuyong. Kinetics and Mechanism of Solution Reacitons-1: Discussion on the Classic Treatments[J]. Chemistry, ;2016, 79(11): 1097-1101. shu

Kinetics and Mechanism of Solution Reacitons-1: Discussion on the Classic Treatments

1.
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100

Corresponding author: Zhang Shuyong,
Received Date: 25 April 2016
Available Online: 30 June 2016

The differences between the reactions occurring in gaseous phase and in solution are demonstrated based on some experimental data. The classic treatment of the solution reactions based on the ‘solvent cage’ and ‘encountered pair’ models and diffusion process is discussed. It is found that, during the classic theoretical treatments, some assumptions and approximation treatments are not reasonable. The rate equation derived from the mechanism formerly proposed is too simple to include some important factors affecting the kinetic characters of the solution reactions.
- Solution reaction,
- Kinetics,
- Solvent cage,
- Diffusion-controlled reaction,
- Mechanism
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