Citation: Shi Wenyan, Chu Yuting, Xu Wei, Shao Rong, Zhang Yuehua. Synthesis and Scale Inhibition Performance of Itaconic Acid-Asparagic Acid-Styrene Sulfonic Sodium Terpolymer[J]. Chemistry, ;2016, 79(11): 1068-1072. shu

Synthesis and Scale Inhibition Performance of Itaconic Acid-Asparagic Acid-Styrene Sulfonic Sodium Terpolymer

Shi Wenyan ¹ ,
Chu Yuting ¹ ,
Xu Wei ¹ ,
Shao Rong ^1,, ,
Zhang Yuehua ²

1.
1 School of Chemistry & Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051;
2.
2 School of Chemistry & Chemical Engineering, Nantong University, Nantong 226007

Corresponding author: Shao Rong,
Received Date: 5 April 2016
Available Online: 6 June 2016
Fund Project:

IA-ASP-SSS terpolymer was prepared from itaconic acid(IA), asparagic acid(ASP) and styrene sulfonic sodium(SSS) by free-radical polymerization in aqueous solution with ammonium persulfate as initiator. The structure of IA-ASP-SSS terpolymer was characterized by infrared spectrum. The effect of monomer ratio, dosage of initiator, reaction temperature and reaction time on IA-ASP-SSS terpolymer's scale inhibition performance were discussed, and the optimum experimental condition was obtained by orthogonal and single factor experiments. Static experiment method was employed to investigate the impact of scale inhibitor dosage and calcium concentration on the scale inhibition efficiency. The results indicate that the scale inhibition efficiency of IA-ASP-SSS terpolymer against calcium carbonate, calcium phosphate and calcium sulphate are all above 95%, when monomer ratio(n_ASP:n_IA:n_SSS) is 1:1:0.1, dosage of initiator is 9% of total mass of monomers, reaction temperature is 85℃ and reaction time is 3h. And as scale inhibitor, IA-ASP-SSS terpolymer is suitable for high hardness water environment.
- Itaconic acid,
- Asparagic acid,
- Styrene sulfonic sodium,
- Free-radical polymerization in aqueous solution,
- Scale inhibition performance
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