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Citation: Ran Ruicheng, Huang Jin, Shen Ji. A POLYMER-SUPPORTED LEWIS ACID CATALYST: POLY(STYRENE-CO-ACRYLONITRILE)-TITANIUM TETRACHLORDDE COMPLEX[J]. Chinese Journal of Applied Chemistry, ;2016, 4(5): 49-54. shu

A POLYMER-SUPPORTED LEWIS ACID CATALYST: POLY(STYRENE-CO-ACRYLONITRILE)-TITANIUM TETRACHLORDDE COMPLEX

Ran Ruicheng ^1,, ,
Huang Jin ² ,
Shen Ji ²

1.
1. Department of Chemistry, Peking University;
2.
2. Department of Applied Chemistry, Beijing Chemical Fiber College

Corresponding author: Ran Ruicheng,
Received Date: 14 June 1986
Available Online: 17 March 1987

The beads of styrene, acrylonitrile(41%) and divinylbenzene (3.6%) copolymer were synthesized and combined with titanium tetrachloride in chloroform to form an n-d bonding complex containing 14.74% of chlorine which correspond to 1.03×10^-3mol TiCl₄/g complex beads. The complex can be used to catalyze many organic reactions in bigh yield, such as esterification, ketal formation, acetalization, etherification and the Friedel-Crafts alkylation. The complex is very stable, it can be reused at least six times and more active than polystyrene-titanium tetrachloride complex^[6].
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