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Citation: Zhuang Wende, Fan Guizhi, Ni Jiazuan. STUDIES ON THE RARE EARTH PHTHALOCYANINE Ⅲ.Solid Reaction of Rare Earth Acetates with Phthalonitrile by DTA Method[J]. Chinese Journal of Applied Chemistry, ;1985, 2(4): 26-30. shu

STUDIES ON THE RARE EARTH PHTHALOCYANINE Ⅲ.Solid Reaction of Rare Earth Acetates with Phthalonitrile by DTA Method

1.
Changchun Institute of Applied Chemistry, Academia Sinica

Corresponding author: Zhuang Wende,
Received Date: 27 December 1984
Available Online: 13 April 1985

In this paper the solid reaction of phthalonitrile and rare earth acetates was studied by DTA method. Contrary to the earlier data from other laboratories. the authors have found that the formation of rare earth phthalocyanines is independent of the heating rate. Two kinds of rare earth coordination compound, i. e. mono-and diphthalocyanine were found in the reaction products, and the ratio of these two compounds varies with the heating rate and the kinds of rare earth used. Higher heating rate such as 20°/min is in favor of the formation of lutetium diphthalocyanine.
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