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Citation: Xu Yun Zhang, Shulin Yuan, Huaxian Liao, . THE HYDROGENATION OF UNSATURATED COMPOUNDS OVER SUPPORTED PALLADIUM CATALYSTS[J]. Chinese Journal of Applied Chemistry, ;1988, 5(5): 71-73. shu

THE HYDROGENATION OF UNSATURATED COMPOUNDS OVER SUPPORTED PALLADIUM CATALYSTS

1.
Dalian Institute of Chemical Physics, Academia Sinica

Received Date: 12 October 1987
Available Online: 16 January 1988
Fund Project:

The behaviors of three supported coordination catalysts,PdCl₂-Tussah silk,PdCl₂-PVP(polyvinylpyrrolidone),PdCl₂-PVP/Al₂O₃ in the hydrogenation of 1-hexene,1-decone,2-ethyl-hexene,crotonaldehyde,cinnamaldehyde and cyclododecatriene were inve-stigated,the activities of these substrates were different from catalyst to catalyst.The hydrogenation rates of the substrates with large space hindranceover PdCl₂-PVP catalyst were higher than that over PdCl₂-Tussah silk catalyst.The larger the space hindrance disparity,the more the difference between the activities of these two catalysts.Most of the substrates show higher activities in reaction over PdCl₂-PVP/Al₂O₃.The hydrogenation selectivities were also different for different catalysts.
- Supported catalyst,
- Palladium catalyst,
- Hydrogenation catalyst
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