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Citation: Kang Beisheng, Liu Hanqin, Wang Fang, Guo Zhi, Cheng Wenzhang, Lu Canzhong, Wang Xinpei, Lu Jiaxi. SYNTHESIS AND STRUCTURAL STUDIES OF Mo-Fe-S COMPOUNDS Ⅵ.CYCLIC VOLTAMMETRIC AND MÖSSBAUER STUDIES ON DOUBLECUBANE CLUSTER COMPOUNDS WITH[MoFe₃S₄] CORE[J]. Chinese Journal of Applied Chemistry, ;1988, 5(5): 67-70. shu

SYNTHESIS AND STRUCTURAL STUDIES OF Mo-Fe-S COMPOUNDS Ⅵ.CYCLIC VOLTAMMETRIC AND MÖSSBAUER STUDIES ON DOUBLECUBANE CLUSTER COMPOUNDS WITH[MoFe₃S₄] CORE

1.
Fujian Institute of Research on the Structure of Matter and Fujian Laboratory of Structural Chemistry, Academia Sinica, Fuzhou

Received Date: 5 November 1987
Available Online: 22 April 1988
Fund Project:

The cyclic voltammetric properties of a series of double-pseudo-cubane cluster compounds (Et₄N)₄[Mo₂Fe₇S₈(SR)₁₂](R=Ph,1;R=o-tolyl,2;R=m-tolyl,3;R=P-tolyl,4)were studied in 0--2.0V vs.SCE.All the compounds showed two redox couples corresponding to the single-electron rcdox reaction of two [MoFe₃S₄]³⁺ cubanc cores respectively.Möss-bauer spectrum of 3·2THF recorded at liquid nitrogen temperature indicates the existence of three types of Fe site in the compound.They are four coordinate 2Fe(Ⅲ)+Fe(Ⅱ)of high spin in the[MoFe₃S₄]³⁺ core with average oxidation state of Fe at+2.67 and six-coordinate Fe(Ⅱ) of high spin in Fe(SR)₆ bridge.
- Cluster compound,
- Double-cubane compound with[MoFe₃S₄],
- Cyclie voltammetry,
- Mössbauer Spectroscopy
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SYNTHESIS AND STRUCTURAL STUDIES OF Mo-Fe-S COMPOUNDS Ⅵ.CYCLIC VOLTAMMETRIC AND MÖSSBAUER STUDIES ON DOUBLECUBANE CLUSTER COMPOUNDS WITH[MoFe3S4] CORE

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SYNTHESIS AND STRUCTURAL STUDIES OF Mo-Fe-S COMPOUNDS Ⅵ.CYCLIC VOLTAMMETRIC AND MÖSSBAUER STUDIES ON DOUBLECUBANE CLUSTER COMPOUNDS WITH[MoFe₃S₄] CORE