Citation:
Qin Chuan, Pang Deren, Ying Jinghua, Huang Baotong. SYNTHESIS AND CHARACTERIZATION OF POLYETHYLENE-b-POLYISOPRENE DIBLOCK COPOLYMERS[J]. Chinese Journal of Applied Chemistry,
;1988, 5(5): 44-47.
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Polybutadiene-b-polyisoprene diblock copolymer(PB-b-PI) was synthesized using anionic polymerization initiated by n-butyllithium.PB segment in it was then uniquely hydrogenated in the presence of cobalt 2-ethylhexanoate/triethylaluminium catalyst,giving poly ethylene-b-polyisoprene diblock copolymer(PE-b-PI).The two diblock copolymers were characterized by infrared analysis,GPC,viscosity,DSC,x-ray diffraction and dynamic mechanical measurements.
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