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Citation: Qian Guoying, Wang Ruiling, Wu Guoliang, Tan Ganzu, Xu Junzhe, Jiao Tianquan. THE EFFECTS OF PLASTICIZERS ON THE PERFORMANCE OF PVC MEMBRANE SODIUM ELECTRODE BASED ON 1,1,1-TRIS[1'-(2'-OXA-4'-OXO-5'AZA 5'-METHYL) DODECYL]PROPANE[J]. Chinese Journal of Applied Chemistry, ;1988, 5(3): 77-80. shu

THE EFFECTS OF PLASTICIZERS ON THE PERFORMANCE OF PVC MEMBRANE SODIUM ELECTRODE BASED ON 1,1,1-TRIS[1'-(2'-OXA-4'-OXO-5'AZA 5'-METHYL) DODECYL]PROPANE

1.
1. Qinghai Institute of Salt Lake, Academia Sinica, Xining;
2.
2. Lanzhou Institute of Chemical Physics, Academia Sinica

Received Date: 18 August 1987
Available Online: 2 December 1987
Fund Project:

The effects of plasticizers and additives on the performance of PVC membrane sodium electrodes based on the title comPound, ETH 227,were investigated. It is shown that electrode with o-nitrophenyl octyl ether(2-NPOE) as plasticizer has the least K_{N_a⁺,K⁺}^pol(=3×10^-3), but the interference of lipophilic anions or divalent cations is serious, the limit of Nernst resPonse is 3×10^-4 mol·dm^-3 NaCl. The linear response range of the electrode with didecyl phthalate as plasticiser, is from 3×10^-5 to 1 mol.dm^-3 NaCl,and K_{N_a⁺,K⁺}^pot<10^-2. incorporating NaSCN would lower the internal resistance of membrane and imProVe the Interference-free ability for lipoPhilie anions.
- Sodium ion-selective electrode,
- Plasticizer,
- Polyvinyl chloride membrane
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