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Citation: Pan Caiyuan, Yuan Jinying. SYNTHESIS AND POLYMERIZATION OF 4-METHYLENE-1, 2-0-ISOPROPYLIDENE-3-METHOXY-α-D-XYLOFURANOSE[J]. Chinese Journal of Applied Chemistry, ;1988, 5(3): 67-72. shu

SYNTHESIS AND POLYMERIZATION OF 4-METHYLENE-1, 2-0-ISOPROPYLIDENE-3-METHOXY-α-D-XYLOFURANOSE

1.
University of Science and Technology of China, Hefei

Received Date: 15 August 1987
Available Online: 6 November 1987

An unsaturated xylofuranose, 4-mehtylene-1, 2-0-isopropylidene-3-methoxy-α-D-xylofu ranose(11) is synthesized. The structural analyses using IR, ¹ H-and ¹³ C-NMR iodicate that a copolymer with addition and ring-opened units were obtained. Upon the structures of polymer, a propagation mechanism was proposed. The polymerization activity, propagation mechanism and polymer structures between the frec radical and cationic polymerization of the unsaturated xylofuranose were discussed.
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