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Citation: Yuan Chengye, Xu Qingren, Hu Shuisheng, Jiang Yadong. SYNTHESIS AND STRUCTURE-REACTIVITY STUDIES OF MONO-BUTYL ESTERS OF OCTYLPHOSPHONATES IN COBALT(Ⅱ) AND NICKEL(Ⅱ) EXTRACTION[J]. Chinese Journal of Applied Chemistry, ;1988, 5(1): 67-70. shu

SYNTHESIS AND STRUCTURE-REACTIVITY STUDIES OF MONO-BUTYL ESTERS OF OCTYLPHOSPHONATES IN COBALT(Ⅱ) AND NICKEL(Ⅱ) EXTRACTION

1.
Shanghai Institute of Organic Chemistry, Academia Sinica

Received Date: 17 February 1987
Available Online: 8 June 1987
Fund Project:

A series of hitherto unknown isomeric monobutyl esters of octylphosphonates was investigated for the structure-reactivity relationship in cobalt and nickel extraction. Linear regression analyses of the apparent extraction equilibrium constants with σ^p constants and Charton's steric parameters v of substituents directly linked to the coordinating moiety of the acidic phosphonates P(O) OH gave, as a rule, excellent results. Since the σ^p values of sudstituents of the compounds under investigation are similar, the correlation analysis between extraction constant and Charton's parameter v also gave satisfactory results. Based on these observation, it was suggested that in the serics of acidic mono-alkyl alkylphosphonates, steric effect plays a predominating rule in the extractive separation of cobalt and nickel.
- Extraction,
- Codalt ion,
- Nickel ion,
- Phosphonic acid ester,
- Structure-property correlation
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