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Citation: Wu Jianhua, Wang Boyi, Zheng Peiju, Xie Gaoyang, Zhang Zhen. THE CRYSTAL STRUCTURE OF NEODYMIUM CHLORIDE WITH DIMETHYL SULFOXIDE[J]. Chinese Journal of Applied Chemistry, ;1988, 5(1): 52-56. shu

THE CRYSTAL STRUCTURE OF NEODYMIUM CHLORIDE WITH DIMETHYL SULFOXIDE

1.
1. Center of Analysis and Measurement, Fudan University, Shanghai;
2.
2. Chemistry Department, Fudan University, Shanghai

Received Date: 24 October 1986
Available Online: 16 February 1987

The crystal structure of [Nd(DMSO)₅(H₂O)₃]Cl₃·H₂O was determined on an ENRAFNONIUS CAD₄ diffractometer with X-ray intensity data collected in 0° < 2θ < 50°. The space group is P₁ with a=9.800(1), b=10.153(1), c=14.757(2)Å; α=93.07(1), β=100.21(1),γ=99.71(1)°, Z=2. The structure was solved by Patterson method and refined with a fullmatrix least-squares procedure to R=0.036. Nd(Ⅲ) ions are coordinated by eight oxygen atoms forming a distorted dodecahedron. The crystal is stabilized through ionic bonds and hydrogen bonds as well.
- Crystall structure,
- Complex,
- Neodymium chloride,
- X-ray diffraction,
- Dimethyl sulfoxide
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