Citation:
Li Youmo, Jia Qingxin, Hong Guangyan, Lu Hongde. EFFECT OF NH4X(X=F.Cl.Br) ON LUMINESCENCE OF LnBO3: Ce3+[J]. Chinese Journal of Applied Chemistry,
;1984, 1(4): 17-22.
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Some LnBO3: Ce3+(Ln=La,Gd or Y) phosphors were synthesized through solid state reaction. It was found that addition of NH4X to LnBO3:Ce3+ during firing increases the luminesence intensity of phosphors without changing the peak positions of excitation and emission spectra. As the radius of Ln3+ decreases and the crystal structure of LnBO3: Ce3+ changes from orthorhombic to hexagonal, the peak position of excitation and emission spectra of LnBO3: Ce3+ shift to longer wavelengths, showing an ob-vious influence of crystal-field on the 5d-4f transition of Ce3+.
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