Citation: Meng Chao, Xu Huan, Huang Lu, Li Dan, Shi Dabin. Synthesis and Luminescent Properties of A New 5-(10-(9-Carboxyanthracenyl)) isophthalic Acid[J]. Chemistry, ;2016, 79(7): 684-687. shu

Synthesis and Luminescent Properties of A New 5-(10-(9-Carboxyanthracenyl)) isophthalic Acid

1.
School of Pharmaceutical Sciences, Zunyi Medical College, Zunyi 563000

Corresponding author: Shi Dabin,
Received Date: 6 December 2015
Available Online: 3 March 2016
Fund Project:

5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)isophthalic acid dimethyl ester (3) was synthesized from 5-amino-isophthalic acid dimethyl ester by diazotization, bromination and Miyaura boration. Moreover, methyl 10-bromo-anthracene-9-carboxylate (6) was synthesized from anthracene-9-carboxylic acid by bromination and esterification. Finally, a new 5-(10-(9-carboxyanthracenyl))-isophthalic acid (8) was synthesized from compound 3 and 6 via Suzuki coupling and hydrolytic reaction. The structure was characterized by ¹H NMR, ¹³C NMR and HRMS. The fluorescent experiments showed that the emission maxima of compound 8 in the aqueous solution is at 425nm, and it possesses blue fluorescent property and good fluorescence quantum efficiency.
- Aromatic multicarboxylic acid,
- Suzuki coupling reaction,
- Fluorescent property
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沈阳化工大学材料科学与工程学院沈阳 110142