Citation: Yang Bizhi, Wang Xinpeng, Ye Jing, Jin Surong, Meng Xianggao. Organic-Inorganic Hybrids Constructed from Keggin Polyoxometalate and Nitrogen Heterocyclic Organic Components[J]. Chemistry, ;2016, 79(7): 650-656. shu

Organic-Inorganic Hybrids Constructed from Keggin Polyoxometalate and Nitrogen Heterocyclic Organic Components

1.
1. School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070;
2.
2. College of Chemistry, Central China Normal University, Wuhan 430072

Corresponding author: Jin Surong,
Received Date: 23 November 2015
Available Online: 30 January 2016
Fund Project:

Two novel organic-inorganic hybrids constructed from Keggin polyoxometalate [Cu^Ⅰ(2,2'-bipy)₂] {[Cu^Ⅰ(2,2'-bipy)₂]₂] [PW₁₂O₄₀]}·4H₂O (1) and {[(H₃bpdc)₃][PW₁₂O₄₀]·H₂bpdc}·2H₂O (2) were synthesized under hydrothermal condition and characterized by elemental analysis, IR, TG, CV and single-crystal X-ray diffraction. Compound 1 crystallized in a monoclinic crystal system, with space group of P2(1)/n, and compound 2 crystallized in a triclinic crystal system, with space group of P1. Compound 1 formed a 2D layered structure by hydrogen bond and π-π stacking, while compound 2 formed a 3D supramolecular architecture by hydrogen bond and electrostatic attraction. The cyclic voltammogram indicated that three couples of redox waves were observed on the compound 1 and 2 modified carbon paste electrode.
- Polyoxometalate,
- In-situ synthesis,
- Crystal structure,
- Organic-inorganic hybrids
1. [1]
  [1] G Kickelbick. Angew. Chem. Int. Ed., 2004, 43:3102~3104.
2. [2]
  [2] 侯占要, 胡敏标, 王维. 化学学报, 2014,72:61~68.
3. [3]
  [3] A Dolbecq, E Dumas, C R Mayer et al. Chem. Rev., 2010, 110:6009~6048.
4. [4]
  [4] B Nohra, H E Moll, L M R Albelo et al. J. Am. Chem. Soc., 2011, 133:13363~13374.
5. [5]
  [5] H Fu, W L Chen, E B Wang et al. Inorg. Chim. Acta, 2009, 362:1412~1420.
6. [6]
  [6] D Y Du, J S Qin, S L Li et al. Chem. Soc. Rev., 2014, 43:4615~4632.
7. [7]
  [7] D W Min, S S Yoon, J H Lee et al. Inorg. Chem. Commun., 2001,4(6):297~300.
8. [8]
  [8] Y C Liang, R Cao, W P Su et al. Angew. Chem. Int. Ed., 2000, 39(18):3304~3307.
9. [9]
  [9] X M Zhang, H H Wu, X M Chen et al. Eur. J. Inorg. Chem., 2003, 25:2959~2964.
10. [10]
  [10] J W Zhao, D Y Shi, J Y Niu et al. Inorg. Chem. Commun., 2010,13(8):822~827.
11. [11]
  [11] L J Zhang, C Y Han, L D Zhng et al. Inorg. Chem. Commun., 2014, 30(8):1904~1910.
12. [12]
  [12] M L Wei, X X Wang, X Y Duan et al. Chem. Eur. J., 2013, 19:1607~1616.
13. [13]
  [13] Z H Wang, X P Wang, S N Zhao et al. Inorg. Chem. Commun., 2013, 29(9):1877~1881.
14. [14]
  [14] S N Zhao, X Y Shao, Z H Wang et al. Acta Chim. Sin., 2010, 68(21):2206~2210.
15. [15]
  [15] L Jia, Y G Chen, C J Zhang et al. J. Mol. Struct., 2009, 921:233.
16. [16]
  [16] N E Brese, M O'Keeffe. Acta Cryst.,1991, B47,192~197.
17. [17]
  [17] A Sengul. Turk. J. Chem., 2004, 28:703~713.
18. [18]
  [18] W G Klemperer, A P Ginsberg. Inorg. Synth., 1990, 27:74~85.
19. [19]
  [19] H Fu, W Chen, E Wang et al. Inorg. Chim. Acta, 2009,362:1412~1420.
1. [1]
  Yuan GAO , Yiming LIU , Chunhui WANG , Zhe HAN , Chaoyue FAN , Jie QIU . A hexanuclear cerium oxo cluster stabilized by furoate: Synthesis, structure, and remarkable ability to scavenge hydroxyl radicals. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 491-498. doi: 10.11862/CJIC.20240271
2. [2]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
3. [3]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
4. [4]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
5. [5]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
6. [6]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
7. [7]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
8. [8]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
9. [9]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
10. [10]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
11. [11]
  Zhaoxin LI , Ruibo WEI , Min ZHANG , Zefeng WANG , Jing ZHENG , Jianbo LIU . Advancements in the construction of inorganic protocells and their cell mimic and bio-catalytical applications. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2286-2302. doi: 10.11862/CJIC.20240235
12. [12]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
13. [13]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
14. [14]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
15. [15]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
16. [16]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
17. [17]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
18. [18]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
19. [19]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
20. [20]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(283)
HTML views(16)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142