Home

Citation: Wang Mingde, Wang Haixia. A New Method for Establishing the Reaction Rate Equation[J]. Chemistry, ;2016, 79(6): 566-569. shu

A New Method for Establishing the Reaction Rate Equation

Wang Mingde ,
Wang Haixia

1.
School of Science, Xi'an Jiaotong University, Xi'an 710049

Received Date: 24 October 2015
Available Online: 27 November 2015

For all reactions with certain reaction order, no matter how the reaction order is, the nonlinear fitting method is applicable. This method can be divided into two steps. In the first step, the reaction order is obtained by nonlinear fitting of the experimental data; in the second step, by the help of reaction order obtained in the first step, the reaction rate constant can be obtained by once more nonlinear fitting of experimental data. Compared with the traditional method of establishing the reaction rate equation, the nonlinear fitting method is easy to operate, and the processing results are concise and accurate.
- Reaction order,
- Reaction rate equation,
- Nonlinear fitting,
- Chemical dynamics
1. [1]
  [1] 张玉军.物理化学(第二版),北京:化学工业出版社,2014:189.
2. [2]
  [2] 郝策,纪敏.多媒体CAI物理化学第六版(下册),大连:大连理工大学出版社,2014:347.
3. [3]
  [3] 傅玉普.物理化学简明教程第三版,大连:大连理工大学出版社,2014:225.
4. [4]
  [4] 刘建兰等.物理化学(下册),北京:化学工业出版社,2014:117.
5. [5]
  [5] 朱志昂,阮文娟.物理化学第五版,北京:科学出版社,2014:238.
6. [6]
  [6] 吕德义,李小年,唐浩东.物理化学(下册),北京:化学工业出版社,2014:224.
7. [7]
  [7] 孙仁义,孙茜.物理化学,北京:化学工业出版社,2014:195.
8. [8]
  [8] 杨永华.物理化学,北京:科学出版社,2015:187.
9. [9]
  [9] 夏海涛.物理化学,北京:化学工业出版社,2015:279.
10. [10]
  [10] 余逸男. 东华大学学报(自然科学版), 2002(3):93~95.
11. [11]
  [11] 胡玮,曹红燕. 大学化学,2006,21(6):43~44.
12. [12]
  [12] 赵玲,彭平安. 环境科学,2008,29(4):972~977.
13. [13]
  [13] 周从山,杨涛. 实验科学与技术,2008,6(3):37~38.
14. [14]
  [14] 王明德,王耿,吴勇.物理化学实验,西安:西安交通大学出版社,2013:147.
1. [1]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
2. [2]
  Jiageng Li , Putrama . 数值积分耦合非线性最小二乘法一步确定反应动力学参数. University Chemistry, 2025, 40(6): 364-370. doi: 10.12461/PKU.DXHX202407098
3. [3]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
4. [4]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
5. [5]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
6. [6]
  Linlin Wu , Yonghua Zhou , Zhongbei Li , Liu Deng , Younian Liu , Limiao Chen , Jianhan Huang . Digital Education Promoting Applied Chemistry Comprehensive Experiments: A Case Study of Catalytic Oxidation of Hydrogen Chloride and Reaction Kinetics. University Chemistry, 2025, 40(9): 273-278. doi: 10.12461/PKU.DXHX202411018
7. [7]
  Xinyu Xu , Jiale Lu , Bo Su , Jiayi Chen , Xiong Chen , Sibo Wang . Steering charge dynamics and surface reactivity for photocatalytic selective methane oxidation to ethane over Au/Ti-CeO₂. Acta Physico-Chimica Sinica, 2025, 41(11): 100153-0. doi: 10.1016/j.actphy.2025.100153
8. [8]
  Yujie WANG , Laobang WANG , Zheng ZHANG , Qi LIU , Jianping LANG . Construction of W/Cu/S cluster-based supramolecular compounds via alkynyl/sulfur cycloaddition and their third-order nonlinear optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2069-2077. doi: 10.11862/CJIC.20250129
9. [9]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
10. [10]
  Shuying Zhu , Shuting Wu , Ou Zheng . Improvement and Expansion of the Experiment for Determining the Rate Constant of the Saponification Reaction of Ethyl Acetate. University Chemistry, 2024, 39(4): 107-113. doi: 10.3866/PKU.DXHX202310117
11. [11]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
12. [12]
  Jichao XU , Ming HU , Xichang CHEN , Chunhui WANG , Leichen WANG , Lingyi ZHOU , Xing HE , Xiamin CHENG , Su JING . Construction and hydrogen peroxide-activated chemodynamic activity of ferrocene?benzoselenadiazole conjugate. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1495-1504. doi: 10.11862/CJIC.20250144
13. [13]
  Ruming Yuan , Pingping Wu , Laiying Zhang , Xiaoming Xu , Gang Fu . Patriotic Devotion, Upholding Integrity and Innovation, Wholeheartedly Nurturing the New: The Ideological and Political Design of the Experiment on Determining the Thermodynamic Functions of Chemical Reactions by Electromotive Force Method. University Chemistry, 2024, 39(4): 125-132. doi: 10.3866/PKU.DXHX202311057
14. [14]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
15. [15]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
16. [16]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
17. [17]
  Jiayu Gu , Siqi Wang , Jun Ling . Kinetics of Living Copolymerization: A Brief Discussion. University Chemistry, 2025, 40(4): 100-107. doi: 10.12461/PKU.DXHX202406012
18. [18]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . 基于激发态手性铜催化的烯烃E→Z异构的动力学拆分——推荐一个本科生综合化学实验. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
19. [19]
  Wenwen Zhang , Peichao Zhang , Conghao Gai , Xiaoyun Chai , Yan Zou , Qingjie Zhao . Unveiling Kinetics at Natural Abundance: ¹³C NMR Isotope Effect Experiments. University Chemistry, 2025, 40(10): 203-207. doi: 10.12461/PKU.DXHX202411076
20. [20]
  Qingtao Niu , Xinyao Xu , Weiyue Yu , Shuxiang Meng , Zhiguo Lv , Manman Jin . Exploration and Practice of Science-Education Integration in Chemical Engineering Thermodynamics Teaching for Chemical Engineering Majors: A Case of Chemical Engineering Physical Property Data Estimation and Chemical Reaction Equilibrium. University Chemistry, 2025, 40(10): 1-9. doi: 10.12461/PKU.DXHX202412029

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(679)
HTML views(117)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return