Citation:
Wang Mingde, Wang Haixia. A New Method for Establishing the Reaction Rate Equation[J]. Chemistry,
;2016, 79(6): 566-569.
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For all reactions with certain reaction order, no matter how the reaction order is, the nonlinear fitting method is applicable. This method can be divided into two steps. In the first step, the reaction order is obtained by nonlinear fitting of the experimental data; in the second step, by the help of reaction order obtained in the first step, the reaction rate constant can be obtained by once more nonlinear fitting of experimental data. Compared with the traditional method of establishing the reaction rate equation, the nonlinear fitting method is easy to operate, and the processing results are concise and accurate.
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[1]
[1] 张玉军.物理化学(第二版),北京:化学工业出版社,2014:189.
-
[2]
[2] 郝策,纪敏.多媒体CAI物理化学第六版(下册),大连:大连理工大学出版社,2014:347.
-
[3]
[3] 傅玉普.物理化学简明教程第三版,大连:大连理工大学出版社,2014:225.
-
[4]
[4] 刘建兰等.物理化学(下册),北京:化学工业出版社,2014:117.
-
[5]
[5] 朱志昂,阮文娟.物理化学第五版,北京:科学出版社,2014:238.
-
[6]
[6] 吕德义,李小年,唐浩东.物理化学(下册),北京:化学工业出版社,2014:224.
-
[7]
[7] 孙仁义,孙茜.物理化学,北京:化学工业出版社,2014:195.
-
[8]
[8] 杨永华.物理化学,北京:科学出版社,2015:187.
-
[9]
[9] 夏海涛.物理化学,北京:化学工业出版社,2015:279.
-
[10]
[10] 余逸男. 东华大学学报(自然科学版), 2002(3):93~95.
-
[11]
[11] 胡玮,曹红燕. 大学化学,2006,21(6):43~44.
-
[12]
[12] 赵玲,彭平安. 环境科学,2008,29(4):972~977.
-
[13]
[13] 周从山,杨涛. 实验科学与技术,2008,6(3):37~38.
-
[14]
[14] 王明德,王耿,吴勇.物理化学实验,西安:西安交通大学出版社,2013:147.
-
[1]
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