Citation:
Qian Jianhua, Liu Jiao, Xing Jinjuan, Xu Jiasheng. Study on Electrical Conductivity of TiO2 Coated by ATO[J]. Chemistry,
;2016, 79(6): 562-565.
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Micro-nano titanium dioxide conductive powder coated by antimony doped tin dioxide was prepared by the chemical co-precipitation method and characterized by XRD and SEM. The effect of the different antimony mass on the conductive properties of powder was examined. The results of cyclic voltammetry (CV) and alternating-current impedance diagrams curves analyzing on the composite electrode prepared by electrochemical workstation showed that with the increase of scanning speed, oxidation and reduction peaks moved to the cathode and anode, respectively, and the shape of the peaks didn't change obviously; when the mass ratio of SnCl4·5H2O and SbCl3 was 10, capacitive reactance arc radius of the sample was the smallest and the slope was the largest, the resistance of the sample was minimum. The conductive performance of the powder sample prepared under the optimized condition was the best, which was in accordance with the results obtained by resistivity measurement using electrical resistivity device. So using AC impedance method and CV to investigate the conductivity of conductive powder was feasible.
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Keywords:
- TiO2,
- SnO2,
- Sb,
- coated,
- Electrical conductivity
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