Citation: Zhang Quanzheng, Cheng Yi, Cheng Xuan, Lu Hongdian, Jiang Rui, He Longzhong, Wang xinghan. Hydrothermal Synthesis and Crystal Structure of a Supermolecular Compound [2-(pyrid-4-yl)benzimidazole]·[SnCl₆][J]. Chemistry, ;2016, 79(6): 558-561. shu

Hydrothermal Synthesis and Crystal Structure of a Supermolecular Compound [2-(pyrid-4-yl)benzimidazole]·[SnCl₆]

1.
1. Department of Chemistry & Materials Engineering, Hefei University, Hefei 230601;
2.
2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002

Received Date: 26 November 2015
Available Online: 23 December 2015
Fund Project:

The supermolecular compound[PyBImH₂]·[SnCl₆] (PyBIm=2-(pyrid-4-yl)benzimidazole) had been synthesized and characterized by elemental analysis, IR, fluorescence spectrum and single-crystal X-ray diffraction. The compound crystallizes in orthorhombic P_bcn space group with the crystal cell parameters:a=7.1468(3) Å, b=15.0493(6) Å, c=16.1195(8) Å, V=1733.72(13) Å³, Z=4, D_c=2.025 g/cm³, M_r=528.63, μ(MoKα)=2.395mm^-1, F(000)=1024. The final R₁=0.0264 and wR₂=0.0665. Sn⁴⁺ is coordinated by six chloride ions in an octahedron geometry.[SnCl₆]^2- anions and[PyBImH₂]²⁺ cations are linked together via hydrogen bonds and π-π stacking interactions, forming a three-dimensional supermolecular framework.
- 2-(Pyrid-4-yl)benzimidazole,
- Supermolecule,
- Hydrothermal synthesis,
- Crystal structure
1. [1]
  [1] J M Lehn. Supramolecular Chemistry, VCH:Weinheim, 1995.
2. [2]
  [2] Y Yang, L T Yan, W G Duan et al. Supramol. Chem., 2012, 24(9~10):707~712.
3. [3]
  [3] C K Xian, X Y Wu, D M Wu et al. Chin. J. Struct. Chem., 2013, 30(3):318~323.
4. [4]
  [4] Q Zhang, X Xu, H Lu et al. Synth. React. Inorg. Metal-Organ. Nano-Metal Chem., 2013, 43(1~2):135~139.
5. [5]
  [5] T Hou, J Bian, X Yue et al. Inorg. Chim. Acta, 2013, 394(3):15~20.
6. [6]
  [6] H Y Liu, J F Ma, Y Y Liu et al. Cryst. Eng. Commun., 2013, 15(14):2699~2708.
7. [7]
  [7] J Y Hu, H C Yao, Y Bai et al. Polyhedron, 2014, 78(1):1~9.
8. [8]
  [8] L Maiore, M C Aragoni, C Deiana et al. Inorg. Chem., 2014, 53(8):4068~4080.
9. [9]
  [9] T Yu, R Liang, Y Zhao et al. Polyhedron, 2015, 85(2):789~794.
10. [10]
  [10] G M Sheldrick, SHELXL-97:Program for Crystal structure Refinement; University of Göttingen, Germany, 1997.
11. [11]
  [11] M Daszkiewicz, M K Marchewka. J.Mol. Struct., 2012, 1017(1):90~97.
12. [12]
  [12] C K Xian, C Z Lu, Q Z Zhang et al. Cryst. Growth Des., 2005, 5(4):1569~1574.
13. [13]
  [13] 郭应臣, 孙汝中, 乔占平等. 无机化学学报, 2009, 25(8):1447~1551.
14. [14]
  [14] 邹惠静, 郭应臣, 闫家伟. 分子科学学报, 2010, 26(2):117~121.
15. [15]
  [15] D F Qiu, Y L Li, H W Wang et al. Chin. J. Struct. Chem., 2010, 29(5):811~815.
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Hydrothermal Synthesis and Crystal Structure of a Supermolecular Compound [2-(pyrid-4-yl)benzimidazole]·[SnCl6]

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通讯作者: 陈斌, bchen63@163.com

Hydrothermal Synthesis and Crystal Structure of a Supermolecular Compound [2-(pyrid-4-yl)benzimidazole]·[SnCl₆]