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Citation: Hong Renjie, Gao Weiqun, Mi Chen, An Dandan, Jiang Yanjun. Preparation and Properties of a Novel Mannitol-Based Oil Gelator[J]. Chemistry, ;2016, 79(6): 539-543. shu

Preparation and Properties of a Novel Mannitol-Based Oil Gelator

1.
School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130

Corresponding author: Jiang Yanjun,
Received Date: 10 August 2015
Available Online: 20 January 2016
Fund Project:

A novel mannitol-based oil gelator was synthesized from cyclohexanone and mannitol through ketal reaction. Factors including reaction time, weight of catalyst, weight of molecular sieve, the ratio of the reactants that influenced on the reaction yield were studied. Under the optimal conditions, that is, 12 g molecular sieve, 0.8 g catalyst, the mole ratio of cyclohexanone to mannitol 6.2:1, and the reaction time 1 h, 52% yield of oil gelator can be achieved. The test of the gelation ability of as-synthesized sugar-based gelator indicated that it can gel several solvents like petrol and silicone oil. The critical gelation concentrations for diesel, petrol and silicone oil were 0.74(wt)%, 2.70(wt)% and 0.39(wt)%, respectively.
- Cyclohexanone mannitol ketal,
- Gelator,
- Cyclohexanone,
- Mannitol,
- Ketal reaction
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