Citation: Cao Xiaohua. Preparation of Y₂P₂W₁₈O₆₂·nH₂O/4A Zeolite and Its Application for Catalytic Synthesis of Acetylsalicylic Acid[J]. Chemistry, ;2016, 79(6): 528-533. shu

Preparation of Y₂P₂W₁₈O₆₂·nH₂O/4A Zeolite and Its Application for Catalytic Synthesis of Acetylsalicylic Acid

Cao Xiaohua

1.
Jiangxi Provincial Engineering Research Center of Ecological Chemical Industry;Key Laboratory of Jiujiang City for Preparation and Application of Organic Functional Molecules;College of Chemical and Environmental Engineering, Jiujiang University, Jiujiang 332005

Received Date: 5 November 2015
Available Online: 21 December 2015
Fund Project:

The Dawson type yttriumphosphotungstates supported on 4A zeolite(Y₂P₂W₁₈O₆₂·nH₂O/4A zeolite)with different loading level were prepared by immersion process and characterized by FT IR, SEM, EDS, NH₃-TPD and N₂ adsorption-desorption. They were applied to the synthesis of acetylsalicylic acid. The influences of catalyst dosage, the mole ratio of reactants, reaction temperature, reaction time and reusability of catalyst on the synthesis were investigated. The results showed that as-prepared yttriumphosphotungstates kept Dawson structure before or after loading on 4A zeolite. Both Y₂P₂W₁₈O₆₂·nH₂O and 40%Y₂P₂W₁₈O₆₂·nH₂O/4A zeolite took the form of spheres. The specific surface area, acid strength and acid amount were enhanced by loading Y₂P₂W₁₈O₆₂·nH₂O on 4A zeolite. The optimal conditions of synthesis reaction were as follows:w (Y₂P₂W₁₈O₆₂·nH₂O/4A zeolite) was 2.3%, the molar ratio of salicylic acid to acetic anhydride was 1:3,reaction temperature of 80℃, reaction time of 30 min. The yield of acetylsalicylic acid could reach 95.2% under the optimum conditions and kept 77.9% after the catalyst being used six times.
- 4A zeolite,
- Yttriumphosphotungstates,
- Dawson structure,
- Acetylsalicylic acid,
- Acid sites
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Preparation of Y₂P₂W₁₈O₆₂·nH₂O/4A Zeolite and Its Application for Catalytic Synthesis of Acetylsalicylic Acid