Citation: Zhao Jie, Lin Qiang, Zhu Qidong, Shi Lei, Dong Haoran. Copolymerization of Propylene Oxide and Phthalic Anhydride Catalyzed by Zn-Ni DMC with Co-complexing Agents Incorporated via Ball Milling[J]. Chemistry, ;2016, 79(6): 523-527. shu

Copolymerization of Propylene Oxide and Phthalic Anhydride Catalyzed by Zn-Ni DMC with Co-complexing Agents Incorporated via Ball Milling

1.
College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158

Corresponding author: Lin Qiang,
Received Date: 5 November 2015
Available Online: 2 February 2016
Fund Project:

Mechanical ball grinding as a rapid and environmentally friendly synthetic method emerges great potential in the solvent-free synthesis of double metal cyanide (DMC) catalysts. Zn-Ni DMCs with small amounts of co-complexing agents (co-CAs) were successfully synthesized through the grinding process. Elemental analysis and FT-IR results indicated that the DMC catalysts were successfully mixed with various co-CAs. The SEM images showed that the resulting DMC catalysts were nanoscale. The DMC complex was proven to be an effective catalyst for the ring-open copolymerization of propylene oxide (PO) with phthalic anhydride (PA) without solvent under controlled reaction condition (6 h, 110℃). For copolymerization, the DMCs showed relatively high activity, and the obtained polyester poly (PO-co-PA) exhibited high molecular weight and narrow polydispersity index.
- Zn-Ni double metal cyanide,
- Co-complexing agents,
- Propylene oxide,
- Phthalic anhydride,
- Ball milling,
- Copolymerization
1. [1]
  [1] J T Garrett, J Runt, J S Lin. Macromolecules, 2002, 35(1):161~168.
2. [2]
  [2] Y Lin, F Hsieh. J. Appl. Polym. Sci.,1997, 65:695~703.[3 J Saito, N Kozawa, H Kunii et al. USP:5145883.1992.
3. [3]
  [4] T Tsuruta, K Matsuura, S Inoue. Makromol. Chem., 1964, 75:211~220.
4. [4]
  [5] S Inoue, K Kitamura, T Tsuruta. Macromol. Chem., 1969, 126(1):250~260.
5. [5]
  [6] T Aida, S Inoue. J. Am. Chem. Soc., 1985, 107(5):1358~1364.
6. [6]
  [7] D J Darensbourg, R R Poland, C Escobedo. Macromolecules, 2012, 45:2242~2248.
7. [7]
  [8] J Liu, W M Ren, Y Liu et al. Macromolecules, 2013, 46(4):1343~1349.
8. [8]
  [9] E H Nejad, A Paoniasari, C G W van Melis et al. Macromolecules, 2013, 46(3):631~637.
9. [9]
  [10] S L James, C J Adams, C Bolm et al. Chem. Soc. Rev., 2012, 41(1):413~417.
10. [10]
  [11] W Zhang, L Lu, Y Cheng et al. Green Chem., 2011,13:2701~2703.
11. [11]
  [12] W Zhang, Q Lin, Y Cheng et al. J. Appl. Polym. Sci., 2012, 123(2):977~985.
12. [12]
  [13] Z F Guo, Q Lin. J. Mol. Catal. A, Chem., 2014, 390:63~68.
13. [13]
  [14] Z F Guo, Q Lin, X H Wang et al. Mater. Lett., 2014,124:184~187.
14. [14]
  [15] Z F Guo, Q Lin, L H Zhu et al. Nanosci. Nanotech. Lett. 2014, 6(4):353~356.
15. [15]
  [16] M M Dharman, J Y Ahn, M K Lee et al. Green Chem., 2008,10:678~684.
16. [16]
  [17] A Peeters, P Valvekens, R Ameloot et al. ACS Catal., 2013,3(4):597~607.
17. [17]
  [18] X H Zhang, R J Wei, X K Sun et al. Polymer, 2011, 52(24):5494~5502.
18. [18]
  [19] A Bemard, C Chatterjee, M H Chisholm, Polymer, 2013, 54(11):2639~2646.
19. [19]
  [20] H S Suh, J Y Ha, J H Yoon et al. React. Funct. Polym., 2010,70(5):288~293.
1. [1]
  Hongling Yuan , Jialin Xie , Jiawei Wang , Jixiang Zhao , Jiayan Liu , Qing Feng , Wei Qi , Min Liu . Cyclic Olefin Copolymer (COC): The Agile Vanguard in the Realm of Materials. University Chemistry, 2024, 39(7): 294-298. doi: 10.12461/PKU.DXHX202311041
2. [2]
  Jianding LI , Junyang FENG , Huimin REN , Gang LI . Proton conductive properties of a Hf(Ⅳ)-based metal-organic framework built by 2,5-dibromophenyl-4,6-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1094-1100. doi: 10.11862/CJIC.20240464
3. [3]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
4. [4]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
5. [5]
  Jiayu Gu , Siqi Wang , Jun Ling . Kinetics of Living Copolymerization: A Brief Discussion. University Chemistry, 2025, 40(4): 100-107. doi: 10.12461/PKU.DXHX202406012
6. [6]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
7. [7]
  Wuxin Bai , Qianqian Zhou , Zhenjie Lu , Ye Song , Yongsheng Fu . Co-Ni Bimetallic Zeolitic Imidazolate Frameworks Supported on Carbon Cloth as Free-Standing Electrode for Highly Efficient Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305041-0. doi: 10.3866/PKU.WHXB202305041
8. [8]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
9. [9]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
10. [10]
  Lu Zhuoran , Li Shengkai , Lu Yuxuan , Wang Shuangyin , Zou Yuqin . Cleavage of C―C Bonds for Biomass Upgrading on Transition Metal Electrocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2306003-0. doi: 10.3866/PKU.WHXB202306003
11. [11]
  Sumiya Akter Dristy , Md Ahasan Habib , Shusen Lin , Mehedi Hasan Joni , Rutuja Mandavkar , Young-Uk Chung , Md Najibullah , Jihoon Lee . Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting. Acta Physico-Chimica Sinica, 2025, 41(7): 100079-0. doi: 10.1016/j.actphy.2025.100079
12. [12]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 2408004-0. doi: 10.3866/PKU.WHXB202408004
13. [13]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
14. [14]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
15. [15]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
16. [16]
  Xichen YAO , Shuxian WANG , Yun WANG , Cheng WANG , Chuang ZHANG . Oxygen reduction performance of self?supported Fe/N/C three-dimensional aerogel catalyst layers. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1387-1396. doi: 10.11862/CJIC.20240384
17. [17]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040
18. [18]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
19. [19]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
20. [20]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(725)
HTML views(71)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142