Citation: Liu Xue, Meng Yanbin, Ma Xuemei, Hu Zhiyong. Synthesis and Property Evaluation of Heterocyclic Corrosion Inhibitor with Surface Activity[J]. Chemistry, ;2016, 79(2): 164-169. shu

Synthesis and Property Evaluation of Heterocyclic Corrosion Inhibitor with Surface Activity

1.
School of Chemical Engineering and Environment, North University of China, Taiyuan 030051

Corresponding author: Hu Zhiyong,
Received Date: 17 June 2015
Available Online: 26 August 2015

A heterocyclic corrosion inhibitor with surface activity was synthesized from 2-aminobenzimidazole, cyanuric chloride, hexanamine and N,N-dimethyl-1,3-propanediamine. Its surface activity was studied through the surface tensions measurement of its hydrochloric acid (HCl) solution with different concentrations. Weight loss method and electrochemical measurements (including potentiodynamic polarization and electrochemical impedance spectroscopy) were used to investigate the inhibition action of the synthesized inhibitor as well as 2-amino-benzimidazole on carbon steel in HCl solution. SEM was used to observe the surface morphology of the test specimens in the weight loss measurement. Results showed that surface activity of as-synthesized inhibitor and the introduced multi-active adsorption centers in it improve its adsorption ability on carbon steel surface, so its inhibition efficiency is better significantly than that of 2-aminobenzimidazole. Inhibition efficiency of the inhibitor increased with increase of its concentrations. The electrochemical measurements showed that the inhibitor was a mixed-type inhibitor.
- Heterocyclic corrosion inhibitor,
- Carbon steel,
- HCl solution,
- Surface activity
1. [1]
  [1] J Y Hu, D Z Zeng, Z Zhang et al. Corr. Sci., 2013, 74:35~43.
2. [2]
  [2] A M Al-Sabagh, N Gh Kandile, N M Nasser et al. Egypt. J. Petrol., 2013, 22(3):351~365.
3. [3]
  [3] B M Mistry, N S Patel, M J Patel et al. Res. Chem. Intermediat., 2011, 37(6):659~671.
4. [4]
  [4] M N El-Haddad, K M Elattar. Res. Chem. Intermediat., 2013, 39(7):3135~3149.
5. [5]
  [5] L Guo, S T Zhang, T M Lv et al. Res. Chem. Intermediat., 2015, 41(6):3729~3742.
6. [6]
  [6] Z Y Cao, Y M Tang, H Cang et al. Corr. Sci., 2014, 83:292~298.
7. [7]
  [7] I B Obot, N O Obi-Egbedi. Corr. Sci., 2010, 52(2):657~660.
8. [8]
  [8] X M Wang, H Y Yang, F H Wang. Corr. Sci., 2011, 53(1):113~121.
9. [9]
  [9] Y M Tang, F Zhang, S X Hu et al. Corr. Sci., 2013, 74:271~282.
10. [10]
  [10] 李杰兰, 梁成浩, 黄乃宝等. 腐蚀科学与防护技术, 2011, 23(2):191~195.
11. [11]
  [11] 胡建春, 李春志, 严奇等. 材料保护, 2011, 44(11):75~79.
12. [12]
  [12] 许立宁, 王兴, 常炜等. 腐蚀与防护, 2012, 33(4):284~288.
13. [13]
  [13] 胡莲跃, 张胜涛, 黄小红等. 材料保护, 2011, 44(8):14~17+88.
14. [14]
  [14] 刘琳, 张月, 邢锦娟. 化学通报, 2012, 75(8):765~768.
15. [15]
  [15] 王秀梅, 万晔, 杨怀玉. 腐蚀科学与防护技术, 2012, 24(4):296~300.
16. [16]
  [16] 李相旭, 杨文忠. 中国腐蚀与防护学报, 2012, 32(2):168~172.
17. [17]
  [17] 宋力, 张帆, 王海平等. 腐蚀与防护, 2013, 34(2):142~146.
18. [18]
  [18] 王娴. 清洗世界, 2012, 28(6):27~33.
19. [19]
  [19] 周雅文, 景姝, 赵莉等. 日用化学工业, 2015, 45(5):247~251.
20. [20]
  [20] M A Malik, M A Hashim, F Nabi et al. Int. J. Electrochem. Sci., 2011, 6:1927~1948.
21. [21]
  [21] I Aiad, M M El-Sukkary, E A Soliman et al. J. Ind. Eng. Chem., 2014, 20(5):3524~3535.
22. [22]
  [22] 谷宁,李春梅. 表面技术, 2003, 32(1):57~65.
23. [23]
  [23] 卢浩, 郭英. 表面技术, 2014, 43(6):69~74.
24. [24]
  [24] K G Zhang, B Xu, W Z Yang et al. Corr. Sci., 2015, 90:284~295.
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沈阳化工大学材料科学与工程学院沈阳 110142