Citation: Shi Ying, Wang Ting, Li Jinping, Wang Shuang. A Supermolecular Chain Assembly of Co₄^Ⅲ Squares and Co^Ⅱ Octahedral Units[J]. Chemistry, ;2016, 79(2): 152-156. shu

A Supermolecular Chain Assembly of Co₄^Ⅲ Squares and Co^Ⅱ Octahedral Units

1.
Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024

Corresponding author: Wang Shuang,
Received Date: 30 June 2015
Available Online: 18 August 2015
Fund Project:

The one-dimensional supermolecular coordination polymer[Co₅(C₅N₂O₄H)₄(C₅N₂O₄H₃)₂(C₁₂N₂H₈)₄(H₂O)₂]·(H₂O)₆ (1) was synthesized by using 4,5-imidazoledicarboxylic acid and Co(NO₃)₂·6H₂O under hydrothermal condition. Single-crystal X-ray analysis revealed that compound 1 crystallizes in the triclinic system, P1 space group with Mr=2082.09, a=13.104(3) Å, b=13.463(3) Å, c=13.708(3) Å, α=75.03(3)^o, β=70.00(3)°, γ=65.39(3)° and V=2046.9 (10) Å³. In compound 1, Co₄^Ⅲ squares and Co^Ⅱ octahedral units are connected with each other via strong hydrogen bonds interactions to construct an one-dimension supermolecular structure. CCDC:977802. Compound 1 was also characterized by PXRD, TGA, IR and elemental analyses.
- Coordination polymer,
- 4,5-Imidazoledicarboxylic acid,
- Metal-organic Square,
- Octahedron
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

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南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com

A Supermolecular Chain Assembly of Co₄^Ⅲ Squares and Co^Ⅱ Octahedral Units