Citation: Guo Hui, Li Jun, Zhang Fengxing. Syntheses of Four Metal Complexes Based on Triaza Macrocycle Derivative Ligand N,N',N"-tris(2-hydroxypropyl)-1,4,7-triazacyclodecane and Their Activities for Promoting Hydrolysis of p-Nitrophenyl Acetate[J]. Chemistry, ;2016, 79(2): 135-140. shu

Syntheses of Four Metal Complexes Based on Triaza Macrocycle Derivative Ligand N,N',N"-tris(2-hydroxypropyl)-1,4,7-triazacyclodecane and Their Activities for Promoting Hydrolysis of p-Nitrophenyl Acetate

1.
1. College of Pharmacy, Shaanxi University of Chinese Medicine, Xianyang 712046;
2.
2. Key Laboratiry of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069

Received Date: 3 July 2015
Available Online: 24 August 2015
Fund Project:

The macrocyclic triamine derivative ligand N,N',N"-tris(2-hydroxypropyl)-1,4,7-triazacyclodecane (L) and its four transition metal complexes[ML]·[ClO₄]₂ (M=Zn²⁺, Cu²⁺, Ni²⁺, Co²⁺) were synthesized and characterized. The complexes possess similar structures. Furthermore, their activities for promoting hydrolysis of 4-nitrophenyl acetate (NA) were also investigated. The results indicated that the k_NA for complexes of Zn²⁺, Cu²⁺, Ni²⁺ and Co²⁺ at pH 7.53 and 25℃ are 22770, 7478, 6331 and 2531 mmol^-1·L·s^-1, respectively, the activity order of center metal for introducing the hydrolysis of NA is Zn > Cu > Ni > Co.
- Macrocyclic triamine derivative,
- Complex,
- Structure,
- Hydrolysis
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