Citation:
Luo Hainan, Ren Lin, Fan Bowen, Xia Yahui. Directional Motion of 1D Active Gel Driven by Light[J]. Chemistry,
;2016, 79(2): 129-134.
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Many living organisms have the instinct that can allow them to alter their properties in response to the stimulation around environments. In the biological realm, light can promote both the positive and negative phototaxis as a powerful stimulus. A one-dimensional active BZ gel was designed; the oscillation frequency of the gel can be controlled by the photosensivity of the BZ reaction catalyzed by Ru-catalyst, which drives the move of gel directionally. At the same time, a responsive gel model proposed by Yashin was modified to simulate the relation between the light intensity and the oscillation frequency of BZ reaction and explain the mechanism of self-sustain motion of active BZ gel. The results may help to design novel smart bionic robot for studying the response to the stimulation from outside environments.
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Keywords:
- Directional motion,
- BZ gel,
- Light,
- Smart robot
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[1]
[1] X He, R S Friedlander, L D Zarzar et al. Chem. Mater., 2013, 25(4):521~523.
-
[2]
[2] P H Raven, R F Evert, S E Eichhorn. Biology of Plants. W H Freeman & Co:New York, 2005.
-
[3]
[3] M P Russell, L M Urbaniak. Echinoderms:Munchen-Heinzeller & Nebelsick, 2004, 04:53~57.
-
[4]
[4] H W Kuhlmann, R Hemmersbach-Krause. Naturwissenschaften, 1993, 80(3):139~141.
-
[5]
[5] D P Hader, G Colombetti, F Lenci et al. Arch. Microbiol., 1981, 130(1):78~82.
-
[6]
[6] P Dayal, O Kuksenok, A C Balazs. Langmuir, 2009, 25(8):4298~4301.
-
[7]
[7] L D Zarzar, J Aizenberg. Acc. Chem. Res., 2014, 47(2):530~539.
-
[8]
[8] J R Capadona, K Shanmuganathan, D J Tyler et al. Science, 2008, 319(5868):1370~1374.
-
[9]
[9] R Yoshida, T Takahashi, T Yamaguchi et al. J. Am. Chem. Soc., 1996, 118(21):5134~5135.
-
[10]
[10] S Shinohara, T Seki, T Sakai et al. Angew. Chem. Int. Ed., 2008, 47(47):9039~9043.
-
[11]
[11] S Maeda, Y Hara, T Sakai et al. Adv. Mater., 2007, 19(21):3480~3484.
-
[12]
[12] R Yoshida, Y Shiraki. Angew. Chem. Int. Ed., 2012, 51:6112~6116.
-
[13]
[13] P Dayal, O Kuksenok, A C Balazs. Macromolecules, 2014, 47(10):3231~3242.
-
[14]
[14] S Sasaki, S Koga, R Yoshida et al. Langmuir, 2003, 19(14):5595~5600.
-
[15]
[15] R Yoshida. Adv. Mater., 2010, 22(31):3463~3483.
-
[16]
[16] L Kuhnert. Nature, 1986, 319(6052):393~394.
-
[17]
[17] T Amemiya, T Yamamoto, T Ohmori et al. J. Phy. Chem. A, 2002, 106(4):612~620.
-
[18]
[18] Y Mori, Y Nakamichi, T Sekiguchi et al. Chem.Phy. Lett., 1993, 211(4~5):421~424.
-
[19]
[19] X Lu, L Ren, Q Gao et al. Chem. Commun., 2013, 49(70):7690~7692.
-
[20]
[20] R D Peacock, I F Fraser. Inorg. Chem., 1985, 24:988~989.
-
[21]
[21] P K Ghosh, T G Spiro. J. Am. Chem. Soc., 1980, 102:5543~5549.
-
[22]
[22] T Amemiya, T Ohmori, T Yamaguchi. J. Phy. Chem. A, 2000, 104(2):336~344.
-
[23]
[23] A Kaminaga, Y Mori, I Hanazaki. Chem. Phy. Lett. 1997, 279(5~6):339~343.
-
[24]
[24] A C Balazs, V V Yashin. Macromolecules, 2006, 39:2024~2026.
-
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-
-
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