Citation: Zha Xianyu, Zhang Dandan, Gao Baojiao. Syntheses of Functional Polysulfones with Bonding Salicylaldehyde-Type Bidentate Schiff Base Ligand on Side Chain and Luminescence Properties of Their Rare Earth Complexes[J]. Chemistry, ;2016, 79(1): 48-55,42. shu

Syntheses of Functional Polysulfones with Bonding Salicylaldehyde-Type Bidentate Schiff Base Ligand on Side Chain and Luminescence Properties of Their Rare Earth Complexes

1.
Department of Chemical Engineering, North University of China, Taiyuan 030051

Corresponding author: Gao Baojiao,
Received Date: 13 May 2015
Available Online: 1 July 2015
Fund Project:

Two bidentate Schiff base ligand-functionalized PSFs, PSF-SAN and PSF-SCA were synthesized by the substitution reaction under optimal conditions, i.e. in N,N-dimethylacetamide at 80℃ from chloromethylated polysulfone (CMPSF) as starting material and the Schiff base reaction in turn. The chemical structures of products were characterized by FT IR and ¹H NMR techniques. Their binary polymer-rare earth (Tb(Ⅲ) ion and Eu(Ⅲ)) ion complexes were prepared, and their photoluminescence properties were preliminarily explored. The PSF-SAN produces strong sensitization action towards Eu(Ⅲ) ion, and the complex PSF-(SAN)₃-Eu(Ⅲ) emits red fluorescence. While the PSF-SCA produce sensitization action towards Tb(Ⅲ) ion, and the complex PSF-(SCN)₃-Tb(Ⅲ) emits green fluorescence.
- Polysulfone,
- Polymer-rare earth complex,
- 4-Hydroxysalicylaldehyde,
- Bidentate Schiff base ligand,
- Sensitization
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沈阳化工大学材料科学与工程学院沈阳 110142