Citation: Wang Jun, Huo Hongliang, Ma Lili, Li Cuiqin, Shi Weiguang. Progress in Catalytic Systems of Decene Synthesis from Ethylene Oligomerization[J]. Chemistry, ;2016, 79(1): 31-36,30. shu

Progress in Catalytic Systems of Decene Synthesis from Ethylene Oligomerization

1.
Heilongjiang Provincial Key Laboratory of Oil & Gas Chemical Technology, School of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318

Corresponding author: Shi Weiguang,
Received Date: 15 June 2015
Available Online: 10 August 2015
Fund Project:

As one of the basic materials in organic synthesis, decene plays an indispensable role in modern chemical production. The demand of decene is increasing year by year, while there is no one process route to produce decene from ethylene oligomerization directly at present. As a long-chain alkene, decene can be prepared by ethylene oligomerization. In this paper, we focused on the reaction of decene synthesis from ethylene oligomerization. We mainly expressed the research status and the achievements in Cr catalytic system which included the effect of the structure of catalysts on the selectivity of decene and the mechanism of polymerization. At the same time, we expounded the research status in Ni catalytic system which included the relationship between the structure of catalysts and the selectivity of decene, and the relationship between the structure of dendritic molecule and the selectivity of decene. Moreover, the progresses of Fe, Ti, Zr catalytic systems in the catalytic synthesis of decene from ethylene oligomerization were also described by some, hoping to provide theory bases for the development of new catalysts for producing decene.
- Decene,
- Ethylene oligomerization,
- Cr based catalysts,
- Ni based catalysts,
- Long chain alkenes
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沈阳化工大学材料科学与工程学院沈阳 110142