Citation:
Chen Guangying, Zhao Bo, Wang Cheng, Jing Ping, Xiao Yu, Niu Meng, Zhao Pengcheng. Gradient Membrane Electrode Assembly of Proton Exchange Membrane Fuel Cell[J]. Chemistry,
;2016, 79(1): 9-15.
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To achieve proton exchange membrane fuel cell long-life high-performance (high power density or high current density) power generation at low cost (low platinum loading), gradient design is introduced into fabrication of MEA. Gradient MEA includes gradient of each MEA assembly:gradient PTFE content and porosity of gas diffusion layer, gradient content of catalyst and Nafion in catalyst layer, and gradient hydrophobicity and porosity of micro-porous layer. Gradient MEA has reasonable distribution of catalyst, porosity and hydrophilicity/hydrophobicity, together with good three phase boundary and multiphase mass transmission channels (e.g. proton,electron,reactant gas and water transmission channels), thus achieving stable high performance of PEMFC at circumstance of low Pt loading, low humidity and high current density. Manufacturing methods, performance and structure-activity relationship of gradient MEA are reviwed in this paper based on the latest research literatures and patents,which has guiding significance for developing of low cost, long-life and high performance MEA.
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