Citation: Chen Aibing, Han Shaochang, Yu Yifeng, Sun Zhongqiang, Zhang Jian, Wang Lei. Ionothermal Synthesis of AlPO₄-42 Molecular Sieves Rapidly at High Temperature[J]. Chemistry, ;2016, 79(3): 264-267,242. shu

Ionothermal Synthesis of AlPO₄-42 Molecular Sieves Rapidly at High Temperature

1.
1. College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018;
2.
2. Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201

Corresponding author: Wang Lei,
Received Date: 18 May 2015
Available Online: 30 September 2015
Fund Project:

In this work, AlPO₄-42 molecular sieves was rapidly synthesized by ionothermal synthesis with phosphoric acid as phosphorus sources and isopropanol aluminum as aluminum sources in ionic liquid [BMIM]Br at 280℃, and some other type aluminophosphate molecular sieves were synthesized by this way. XRD, SEM, BET and solid-state mas NMR were used to investigate the influence of the ratio of materials, template agent and different crystallization time on synthesis. The specific surface area, size of the entrance and filler in the pore for as-prepared AlPO₄-42 molecular sieves were characterized as well. The results indicated that the structure of AlPO₄-42 molecular sieves has been already formed after 4 min. The synthesized AlPO₄-42 molecular sieves had a tetrakaidecahedron morphology, which is obviously different with the AlPO₄-42 molecular sieves of cube morphology obtained by conventional approach, and the specific surface area and pore volume of AlPO₄-42 molecular sieves were changed too. In the process of synthesis AlPO₄-42 molecular sieves, the coordinated action of ionic liquid and template led to form the products.
- Ionothermal,
- Rapid synthesis,
- AlPO₄-42 molecular sieves
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沈阳化工大学材料科学与工程学院沈阳 110142

Ionothermal Synthesis of AlPO4-42 Molecular Sieves Rapidly at High Temperature

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通讯作者: 陈斌, bchen63@163.com

Ionothermal Synthesis of AlPO₄-42 Molecular Sieves Rapidly at High Temperature