Home

Citation: Pan Wanli, Chen Changzhong, Liu Wenmin, Peng Kelin. Synthesis and Properties of Polymeric Solid-Solid Phase Change Material Based on the Skeleton of Hexahydroxy Compounds[J]. Chemistry, ;2016, 79(3): 254-258. shu

Synthesis and Properties of Polymeric Solid-Solid Phase Change Material Based on the Skeleton of Hexahydroxy Compounds

1.
School of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang 473061

Corresponding author: Liu Wenmin,
Received Date: 28 July 2015
Available Online: 8 October 2015
Fund Project:

Three kinds of new polymeric solid-solid phase change meterials (SSPCMs) with different crosslinking structures were synthesized and characterized for thermal energy storage. In the SSPCMs, the hexahydroxy compounds sorbitol, dipentaerythritol and inositol were individually employed as the molecular skeleton and polyethylene glycol (PEG) was used as the phase change functional chain. The molecular structure, crystalline properties, phase change behaviors, thermal reliability and stability of the synthesized SSPCMs were investigated by FT IR, XRD, POM, DSC and TG, respectively. The results showed that the synthesized SSPCMs have high thermal energy storage density and an applicable temperature range of 30~70℃, and the maximum phase change enthalpy in the heating and cooling process for them is 107.5J·g^-1 and 102.9J·g^-1, respectively. They have good reusability, excellent thermal reliability and stability from the heating-cooling thermal cycle test and TG curves. So they have potential application in the areas of thermal energy storage and temperature-control.
- Solid-solid phase change materials,
- Phase transition properties,
- Polyethylene glycol,
- Thermal energy storage
1. [1]
  [1] R Parameshwaran, S Kalaiselvam, S Harikrishnan et al. Renew. Sust. Energ. Rev., 2012, 16:2394~2433.
2. [2]
  [2] P B Salunkhe, P S Shembekar. Renew. Sust. Energ. Rev., 2012, 16:5603~5616.
3. [3]
  [3] 何丽红, 李文虎, 李菁若等. 材料导报, 2014, 28:71~74.
4. [4]
  [4] 刘杰. 陶瓷, 2014, 2:30~32.
5. [5]
  [5] D Zhou, C Y Zhao, Y Tian. Appl. Energ., 2012, 92:593~605.
6. [6]
  [6] C Alkan, E Gunther, S Hiebler et al. Solar Energy, 2012, 86:1761~1769.
7. [7]
  [7] A Sari, C Alkan, A Bicer. Mater. Chem. Phys., 2012, 133:87~94.
8. [8]
  [8] P Xi, Y Duan, P Fei et al. Eur. Polym. J., 2012, 48:1295~1303.
9. [9]
  [9] Y Li, S Wang, H Liu et al. Sol. Energy Mater. Sol. Cells, 2014, 127:92~97.
10. [10]
  [10] K Chen, R Liu, C Zou et al. Sol. Energy Mater. Sol. Cells, 2014, 130:466~473.
11. [11]
  [11] C Chen, W Liu, Z Wang et al. Sol. Energy Mater. Sol. Cells, 2015, 134:80~88.
1. [1]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
2. [2]
  Yingtong Shi , Guotong Xu , Guizeng Liang , Di Lan , Siyuan Zhang , Yanru Wang , Daohao Li , Guanglei Wu . PEG-VN改性PP隔膜用于高稳定性高效率锂硫电池. Acta Physico-Chimica Sinica, 2025, 41(7): 100082-0. doi: 10.1016/j.actphy.2025.100082
3. [3]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
4. [4]
  Yuanyuan Ping , Wangqing Kong . 光催化碳氢键官能团化合成1-苯基-1,2-乙二醇. University Chemistry, 2025, 40(6): 238-247. doi: 10.12461/PKU.DXHX202408092
5. [5]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF-Templated Synthesis of Nitrogen-Doped Carbon for Enhanced Electrochemical Sodium Ion Storage and Removal. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-0. doi: 10.3866/PKU.WHXB202405002
6. [6]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 2309036-0. doi: 10.3866/PKU.WHXB202309036
7. [7]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
8. [8]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
9. [9]
  Xianglan Zhang , Jingwen Ma , Junya Cao , Weibin Cai , Zhibing Chang , Jinchang Liu . “价值引领，固基强能”的化工原理教改与实践. University Chemistry, 2025, 40(8): 11-17. doi: 10.12461/PKU.DXHX202410041
10. [10]
  Chunling Qin , Shuang Chen , Hassanien Gomaa , Mohamed A. Shenashen , Sherif A. El-Safty , Qian Liu , Cuihua An , Xijun Liu , Qibo Deng , Ning Hu . Regulating HER and OER Performances of 2D Materials by the External Physical Fields. Acta Physico-Chimica Sinica, 2024, 40(9): 2307059-0. doi: 10.3866/PKU.WHXB202307059
11. [11]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . Strategies for enhancing capacity and rate performance of two-dimensional material-based supercapacitors. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-0. doi: 10.1016/j.actphy.2025.100063
12. [12]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
13. [13]
  Xiaohang JIN , Qi LIU , Jianping LANG . Room‑temperature solid‑state synthesis, structure, and third‑order nonlinear optical properties of phosphine‑ligand‑protected silver thiolate clusters. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1505-1512. doi: 10.11862/CJIC.20250125
14. [14]
  Jiaqi Chen , Chunhui Luan , Yue Sun , Qiyun Ma , Wangfei Hao , Yanjia Wang , Xu Wu . Understanding the Dynamics of Heat and Cold through Chemistry: The Interplay of Chemical Energy and Thermal Energy. University Chemistry, 2024, 39(9): 214-223. doi: 10.12461/PKU.DXHX202312020
15. [15]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
16. [16]
  Mengyang LI , Hao XU , Zhonghao NIU , Chunhua GONG , Weihui ZHONG , Jingli XIE . Highly effective catalytic synthesis of β-amino alcohols by using viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1294-1300. doi: 10.11862/CJIC.20250080
17. [17]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
18. [18]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
19. [19]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
20. [20]
  Yihan Xue , Xue Han , Jie Zhang , Xiaoru Wen . NCQDs修饰FeOOH基复合材料的制备及其电容脱盐性能. Acta Physico-Chimica Sinica, 2025, 41(7): 100072-0. doi: 10.1016/j.actphy.2025.100072

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(408)
HTML views(62)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return