Citation: Liu Xingpeng, Hong Tao, Huang Kama. The Polarization of Chemical Reactions under the Action of Electromagnetic Wave[J]. Chemistry, ;2016, 79(4): 377-380. shu

The Polarization of Chemical Reactions under the Action of Electromagnetic Wave

1.
College of Electronics and Information Engineering, Sichuan University, Chengdu 610029

Corresponding author: Huang Kama,
Received Date: 8 October 2015
Available Online: 27 November 2015
Fund Project:

Microwave-assisted chemical reactions have attracted interest for decades, but hot spots and thermal runaway prevent the further development of microwave heating in chemical engineering. In order to solve these problems, it is needed to study the interaction between electromagnetic wave and chemical reactions. The polarization of the chemical reactions is the basis to investigate the interaction between electromagnetic wave and chemical reactions. The expression of polarization of the polar-molecule reactions is derived with modified Smoluchowski-Debye equation. The polarization of the chemical reactions is actually a response of a linear time varying system, which is a Markov process under certain conditions. The aim of this paper is to discuss the relation between the time domain and the frequency domain representation of the polarization of chemical reactions, along with the limitations of the representation in the frequency domain.
- Polarization,
- Smoluchowski-Debye equation,
- Response function,
- Permittivity
1. [1]
  [1] R Gedye, F Smith, K Westaway et al. Tetrahed. Lett, 1986, 27:279~282.
2. [2]
  [2] D A Jones, T P Lelyveld, S D Mavrofidis et al. Resour. Conserv. Recy., 2002, 34:75~90.
3. [3]
  [3] T Santos, M A Valente, J Monteiro et al. Appl. Therm. Eng., 2011, 31:3255~3261.
4. [4]
  [4] R Vadivambal, D S Jayas. Food Bioproc. Tech., 2010, 3:161~171.
5. [5]
  [5] X Zhang, D O Hayward, D M P Mingos. Catal. Lett., 2003, 88:33~38.
6. [6]
  [6] C O Kappe. Chem. Soc. Rev., 2008, 37:1127~1139.
7. [7]
  [7] G Roussy, A Bennani, J M Thiebaut. J. Appl. Phys., 1987, 62:1167~1170.
8. [8]
  [8] H Lehmann, L LaVecchia. Org. Proc. Res. Dev., 2010, 14:650~656.
9. [9]
  [9] C O Kappe, B Pieber, D Dallinger. Angew. Chem. Int. Ed., 2013, 52:1088~1094.
10. [10]
  [10] S Sudo, N Oshiki, N Shinyashiki et al. J. Phys. Chem. A, 2007. 111:2993~2998.
11. [11]
  [11] S Sun, X Hu, Y Xia. Appl. Biochem. Biotech., 2012, 166:1454~1462.
12. [12]
  [12] W Scheider. Biophys. J., 1965, 5:617~628.
13. [13]
  [13] G Schwarz. J. Phys. Chem., 1967, 71:4021~4030.
14. [14]
  [14] K Huang, H Zhu, L Wu. Bioresour. Technol., 2013, 131:541~544.
15. [15]
  [15] H C Zhu, X Q Yang, K M Huang. J. Solut. Chem., 2012, 41:1729~1737.
16. [16]
  [16] X Yang, K Huang. IEEE Trans. Geosci. Remote, 2005, 43:315~320.
17. [17]
  [17] K M Huang, X Yang. PIER, 2008, 5:99~107.
18. [18]
  [18] T Hong, K Huang. J. Phys. Org. Chem., 2015, 28:414~417.
19. [19]
  [19] K Huang, T Hong. J. Phys. Chem. A, 2015, 119:8898~8902.
20. [20]
  [20] W T Coffey, B V Paranjape. P. Roy. Soc. A-Math. Phys., 1978, 78:17~25.
21. [21]
  [21] G H Czerlinski. Chemical relaxation, New York:Dekker, 1966.
22. [22]
  [22] Z Sekkat, J Wood, W Knoll. J. Phys. Chem., 1995, 99:17226~17234.
23. [23]
  [23] 李景德,沈韩,陈敏. 电介质理论. 北京:科学出版社, 2003. 63~69.
24. [24]
  [24] S R de Groot, P Mazur. Non-equilibrium thermodynamics, North Chelmsford:Courier Corporation, 2012.
25. [25]
  [25] C Dykstra, G Frenking, K Kim et al. Theory and applications of computational chemistry:the first forty years. Amsterdam:Elsevier, 2011.
26. [26]
  [26] 李如生. 平衡和非平衡统计力学. 北京:清华大学出版社, 1995:171~202.
27. [27]
  [27] N G van Kampen. Stochastic processes in physics and chemistry. Amsterdam:Elsevier, 1992.
28. [28]
  [28] C T Chen. Linear system theory and design. New York Oxford:Oxford University Press, 1995.
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沈阳化工大学材料科学与工程学院沈阳 110142