Citation: Zhu Hanlin, Liang Kuang. Study on Visible-Light Photocatalytic Properties of Oxygen Defect SnO₂ Nanoparticles[J]. Chemistry, ;2016, 79(4): 327-331,348. shu

Study on Visible-Light Photocatalytic Properties of Oxygen Defect SnO₂ Nanoparticles

Zhu Hanlin ¹ ,
Liang Kuang ²

1.
1. The Affiliated High School of University of Science and Technology of China, Hefei 230026;
2.
2. Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026

Received Date: 13 August 2015
Available Online: 20 October 2015

A novel photocatalyst consisting of oxygen-deficient SnO₂ nanoparticles which can effectively degrade methyl orange (MO) under visible light was synthesized by a simple hydrothermal method and characterized by XRD, TEM, HRTEM and UV-Vis diffuse reflectance spectra. The results showed that the band gap of as-prepared catalyst can be lowered to 2.90eV, and thus the visible light absorption of the catalyst can be enhanced. The photocatalytic activity of the as-prepared catalyst was evaluated by degradation of methyl orange (MO) under irradiation of visible light. The degradation rate of MO (10 mg/L) by oxygen-deficient SnO₂ nanoparticles (1g/L) can reach above 99% in 40 min under visible light illumination. Because of simple synthesis, high catalytic performance, low costs and mild reaction environment, the synthesized catalyst provides a new approach to solve the problem of organic dyes pollution in environment.
- Oxygen defect,
- SnO₂,
- Hydrothermal synthesis,
- Methyl orange,
- Photocatalytic degradation
1. [1]
  [1] D Wang, L Guo, Y Zhen et al. J. Mater. Chem. A, 2014, 2(30):11716~11727.
2. [2]
  [2] 马瑞, 万霞, 铁绍龙. 华南师范大学学报:自然科学版, 2014, 46(2):61~66.
3. [3]
  [3] 施冬梅, 李再兴, 多金环. 环境科学与技术, 2002, 25(5):46~48.
4. [4]
  [4] A Kocakuşakoğlu, M Dağlar, M Konyar et al. J.Eur. Ceramic Soc., 2015, 35(10):2845~2853.
5. [5]
  [5] 张红美, 孔德国, 罗华平等.湖北农业科学, 2012, (22):5048~5050.
6. [6]
  [6] X Zhang, X B Wang, L W Wang et al. ACS Appl. Mater. Interf., 2014, 6(10):7766~7772.
7. [7]
  [7] 赵伟荣, 施巧梦, 刘莹. 物理化学学报, 2014, 30(7):1318~1324.
8. [8]
  [8] T K Jana, A Pal, K Chatterjee. J. Alloys Compd., 2014, 583:510~515.
9. [9]
  [9] L Fu, Y Zheng, Q Ren et al. J. Ovonic Res., 2015, 11(1):21~26.
10. [10]
  [10] 陈薇, 孙丰强. 华南师范大学学报:自然科学版, 2014, 46(3):56~59.
11. [11]
  [11] 王艺聪, 张晓凤, 曾嘉莹等. 材料导报, 2011, 25(16):70~74.
12. [12]
  [12] R Yin, Q Luo, D Wang et al. J. Mater. Sei.,2014, 49(17):6067~6073.
13. [13]
  [13] L P Singh, M N Luwang, S K Srivastava. New J. Chem., 2014, 38(1):115~121.
14. [14]
  [14] 郭龙发, 潘海波, 沈水发等. 催化学报, 2009, 30(1):53~59.
15. [15]
  [15] F M Hossain, G E Murch, L Sheppard et al. Solid State Ionics, 2007, 178(5):319~325.
16. [16]
  [16] X Pan, M Q Yang, X Fu et al. Nanoscale, 2013, 5(9):3601~3614.
17. [17]
  [17] X Liu, S Gao, H Xu et al. Nanoscale, 2013, 5(5):1870~1875.
18. [18]
  [18] X Bai, L Wang, R Zong et al. Langmuir, 2013, 29(9):3097~3105.
19. [19]
  [19] M Li, Y Hu, S Xie et al. Chem. Commun., 2014, 50(33):4341~4343.
20. [20]
  [20] A Kar, S Sain, S Kundu et al. ChemPhysChem, 2015, 16(5):1017~1025.
21. [21]
  [21] Z Zheng, B Huang, X Meng et al. Chem. Commun., 2013, 49(9):868~870.
22. [22]
  [22] H Choi, J D Song, K R Lee et al. Inorg. Chem., 2015, 54(8):3759~3765.
23. [23]
  [23] R Zha, R Nadimicherla, X Guo. J. Mater. Chem. A, 2015, 3(12):6565~6574.
24. [24]
  [24] L Sun, Y Qin, Q Cao et al. Chem. Commun., 2011, 47(47):12628~12630.
25. [25]
  [25] B Chai, X Liao, F Song et al. Dalton Transac., 2014, 43(3):982~989.
26. [26]
  [26] Y Ding, F Yang, L Zhu et al. Appl. Catal. B:Environ., 2015, 164:151~158.
27. [27]
  [27] Y Liu, Y Jiao, Z Zhang et al. ACS Appl. Mater. Interf., 2014, 6(3):2174~2184.
28. [28]
  [28] Y Cho, W Choi, C H Lee et al. Environ. Sci. Technol., 2001, 35(5):966~970.
29. [29]
  [29] R Velmurugan, M Swaminathan. Solar Energy Mater. Solar Cells, 2011, 95(3):942~950.
1. [1]
  Yameen Ahmed , Xiangxiang Feng , Yuanji Gao , Yang Ding , Caoyu Long , Mustafa Haider , Hengyue Li , Zhuan Li , Shicheng Huang , Makhsud I. Saidaminov , Junliang Yang . Interface Modification by Ionic Liquid for Efficient and Stable FAPbI₃ Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(6): 2303057-0. doi: 10.3866/PKU.WHXB202303057
2. [2]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
3. [3]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
4. [4]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
5. [5]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
6. [6]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
7. [7]
  Junjie TANG , Yunting ZHANG , Zhengjiang LIU , Jiani WU . Preparation of CeO₂ by starch template method for photo-Fenton degradation of methyl orange. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1617-1631. doi: 10.11862/CJIC.20240420
8. [8]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-0. doi: 10.3866/PKU.WHXB202407021
9. [9]
  Zhinan GUO , Junli WANG , Qiang ZHAO , Zhifang JIA , Zuopeng LI , Kewei WANG , Yong GUO . Cu₂O/Bi₂CrO₆ Z-scheme heterojunction: Construction and photocatalytic degradation properties for tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 741-752. doi: 10.11862/CJIC.20240403
10. [10]
  Qingwang LIU . MoS₂/Ag/g-C₃N₄ Z-scheme heterojunction: Preparation and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 821-832. doi: 10.11862/CJIC.20240148
11. [11]
  Jingyi Xie , Qianxi Lü , Weizhen Qiao , Chenyu Bu , Yusheng Zhang , Xuejun Zhai , Renqing Lü , Yongming Chai , Bin Dong . Enhancing Cobalt―Oxygen Bond to Stabilize Defective Co₂MnO₄ in Acidic Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305021-0. doi: 10.3866/PKU.WHXB202305021
12. [12]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
13. [13]
  Juan CHEN , Guoyu YANG . A porous-layered aluminoborate built by mixed oxoboron clusters and AlO₄ tetrahedra. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 193-200. doi: 10.11862/CJIC.20240341
14. [14]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . Modulating reactive oxygen species in O, S co-doped C₃N₄ to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-0. doi: 10.1016/j.actphy.2025.100052
15. [15]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
16. [16]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
17. [17]
  Jimin HOU , Mengyang LI , Chunhua GONG , Shaozhuang ZHANG , Caihong ZHAN , Hao XU , Jingli XIE . Synthesis, structures, and properties of metal-organic frameworks based on bipyridyl ligands and isophthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 549-560. doi: 10.11862/CJIC.20240348
18. [18]
  Meiran Li , Yingjie Song , Xin Wan , Yang Li , Yiqi Luo , Yeheng He , Bowen Xia , Hua Zhou , Mingfei Shao . Nickel-Vanadium Layered Double Hydroxides for Efficient and Scalable Electrooxidation of 5-Hydroxymethylfurfural Coupled with Hydrogen Generation. Acta Physico-Chimica Sinica, 2024, 40(9): 2306007-0. doi: 10.3866/PKU.WHXB202306007
19. [19]
  Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO₂ nanotube array modified Ti-based Ni-Sb co-doped SnO₂ anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262
20. [20]
  Mengyang LI , Hao XU , Zhonghao NIU , Chunhua GONG , Weihui ZHONG , Jingli XIE . Highly effective catalytic synthesis of β-amino alcohols by using viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1294-1300. doi: 10.11862/CJIC.20250080

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(386)
HTML views(32)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Study on Visible-Light Photocatalytic Properties of Oxygen Defect SnO2 Nanoparticles

Metrics

通讯作者: 陈斌, bchen63@163.com

Study on Visible-Light Photocatalytic Properties of Oxygen Defect SnO₂ Nanoparticles