Citation: Xiang Tianchen, Zhao Qiang, Xue Yujing, Yan Kangping. Study on Preparation of Ni-P Micro-Arrays Material with Etched Porous Aluminum Template and Its Electrocatalytic Performance[J]. Chemistry, ;2016, 79(4): 321-326. shu

Study on Preparation of Ni-P Micro-Arrays Material with Etched Porous Aluminum Template and Its Electrocatalytic Performance

1.
College of Chemical Engineering, Sichuan University, Chengdu 610065

Corresponding author: Yan Kangping,
Received Date: 12 September 2015
Available Online: 23 October 2015

Ni-P micro-arrays material was fabricated by electroless plating method with etched porous aluminum template. The microstructure and elemental composition of the material were analyzed by SEM, EDS and XRD. Electrochemical measurements were performed to study the effect of plating temperature and time on the hydrogen evolution over-potential of Ni-P micro-arrays electrodes. The results showed that Ni-P micro-arrays electrode fabricated at 70℃ exhibits the highest electrocatalytic activity for hydrogen evolution reaction, and the over-potential was reduced by 100mV compared with the smooth Ni-P electrodes at 15 mA/cm². Its exchange current density reached to 13.53×10^-6A/cm² which is about 10 times of the smooth group. Ni-P micro-arrays electrode has already formed the array structures completely after fabricated at 70℃ for 4h, it exhibits a low over-potential but no longer benefited from increasing time further. To characterize the catalytic performance of obtained coatings intuitively, photocatalytic water splitting experiments were performed in a two-compartment photoelectrochemical cell. As the cathode, Ni-P micro-arrays electrode shows a high hydrogen production rate which is about 200% faster than that of the smooth group.
- Etched porous aluminum,
- Electroless Ni-plating,
- Array structure,
- Hydrogen evolution reaction
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沈阳化工大学材料科学与工程学院沈阳 110142