Citation: Dai Shengping, Kong Xiangfei, Wang Guixia, Xia Liting, Liu Peng, Yu Caili. Advances in Asymmetric meso-Substituted Porphyrins[J]. Chemistry, ;2016, 79(4): 314-320. shu

Advances in Asymmetric meso-Substituted Porphyrins

1.
College of Chemistry and Biological Engineering, Guilin University of Technology, Guilin 541004

Corresponding author: Kong Xiangfei,
Received Date: 11 August 2015
Available Online: 16 November 2015
Fund Project:

Porphyrins widely exist in nature and have a wide range of applications in the fields of the molecular self-assembly, biomimicry, electrochemistry, analytical chemistry, catalysis chemistry, and so on. Porphyrins with a variety of meso-substituents show different chemical properties, which have attracted wide attention. In this paper, the structural characteristics, physical and chemical properties of porphyrins were simply introduced firstly. Secondly, the tetraphenyl porphyrin which had relatively simple structures was chosen as example, its reaction mechanism was discussed. Thirdly, three kinds of synthetic methods for asymmetric meso-substituted porphyrins, i.e. mixed condensation synthesis, total synthesis and synthesis of preformed functionalization were described detailedly. Finally, the research progress of porphyrins in recent years was summarized and their development and application in the future were prospected.
- Asymmetric porphyrin,
- meso-Substituted,
- Reaction mechanism,
- Synthetic method
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