Home

Citation: Zhang Xueyu, Yu Haifeng, Diao Quanping, Yin Jianan, Xi Chunmei, Wu Yue. FeCl₃·6H₂O-Mediated Deacetylation/Decarboxylation of α-Carbonyl-α-aceto/Carboxyl Cyclic Ketene Dithioacetals[J]. Chemistry, ;2016, 79(5): 459-462. shu

FeCl₃·6H₂O-Mediated Deacetylation/Decarboxylation of α-Carbonyl-α-aceto/Carboxyl Cyclic Ketene Dithioacetals

1.
School of Chemistry and Life Science, Anshan Normal University, Anshan 114007

Corresponding author: Yu Haifeng,
Received Date: 11 September 2015
Available Online: 14 November 2015
Fund Project:

An inexpensive and environmentally friendly FeCl₃·6H₂O-mediated deacetylation/decarboxylation of α-carbonyl-α-aceto/carboxyl cyclic ketene dithioacetals had been developed. The procedure was characterized by mild reaction condition, environmentally benign and simplicity.
- Cyclic ketene dithioacetals,
- Iron (III) chloride,
- Deacetylation,
- Decarboxylation
1. [1]
  [1] 宋阳, 唐雪松, 侯晓萌等. 有机化学, 2013, 33: 76~89.
2. [2]
  [2] L Pan, Q Liu. Synlett, 2011, 8: 1073~1080.
3. [3]
  [3] L Pan, X H Bi, Q Liu. Chem. Soc. Rev., 2013, 42: 1251~1286.
4. [4]
  [4] 刘群, 朱再明, 杨智蕴等. 高等学校化学学报, 1993, 14: 1100~1102.
5. [5]
  [5] 张殊佳, 刘群, 朱再明等. 高等学校化学学报, 1994, 15: 1155~1158.
6. [6]
  [6] 赵玉龙, 刘群, 张薇等. 高等学校化学学报, 2006, 27: 482~484.
7. [7]
  [7] H F Yu, W W Jin, C L Sun et al. Angew. Chem. Int. Ed. 2010, 49: 5792~5797.
8. [8]
  [8] H F Yu, Y M Zhang, T C Li et al. RSC Adv. 2015, 5: 11293~11296.
9. [9]
  [9] H F Yu. Synth. Commun., 2013, 43: 1280~1286.
10. [10]
  [10] 于海丰, 廖沛球. 化学通报, 2013, 76(5)：435~439.
11. [11]
  [11] H F Yu. Chin. J. Chem. 2012, 23: 367~371.
12. [12]
  [12] 于海丰，廖沛球. 高等学校化学学报, 2012, 33: 1969~1972.
13. [13]
  [13] 于海丰, 王东来, 赵辉等. 有机化学, 2011, 31: 1949~1960.
14. [14]
  [14] 于海丰, 李铁纯, 廖沛球等. 有机化学, 2014, 34: 956~961.
15. [15]
  [15] 于海丰, 廖沛球, 刁全平等. 有机化学, 2014, 34: 1851~1856.
16. [16]
  [16] H F Yu, T C Li, P Q Liao. Synthesis, 2012, 44: 3743~3756.
17. [17]
  [17] 赵辉, 张福维, 于海丰等. 有机化学, 2015, 35:1493~1499.
18. [18]
  [18] 于海丰, 肖幼萍, 刘群等. 高等学校化学学报, 2004, 25: 673~675.
19. [19]
  [19] J Liu, M Wang, F Han et al. J. Org. Chem. 2009, 74: 5090~5092.
20. [20]
  [20] Q Zhang, S G Sun, J L Hu et al. J. Org. Chem, 2007, 72: 139~143.
1. [1]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
2. [2]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
3. [3]
  Zhongyan Cao , Youzhi Xu , Menghua Li , Xiao Xiao , Xianqiang Kong , Deyun Qian . Electrochemically Driven Denitrative Borylation and Fluorosulfonylation of Nitroarenes. University Chemistry, 2025, 40(4): 277-281. doi: 10.12461/PKU.DXHX202407017
4. [4]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
5. [5]
  Chaolin Mi , Yuying Qin , Xinli Huang , Yijie Luo , Zhiwei Zhang , Chengxiang Wang , Yuanchang Shi , Longwei Yin , Rutao Wang . Galvanic Replacement Synthesis of Graphene Coupled Amorphous Antimony Nanoparticles for High-Performance Sodium-Ion Capacitor. Acta Physico-Chimica Sinica, 2024, 40(5): 2306011-0. doi: 10.3866/PKU.WHXB202306011
6. [6]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
7. [7]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
8. [8]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 2408015-0. doi: 10.3866/PKU.WHXB202408015
9. [9]
  Tongyan Yu , Pan Xu . Visible-Light Photocatalyzed Radical Rearrangement Reaction. University Chemistry, 2025, 40(7): 169-176. doi: 10.12461/PKU.DXHX202409070
10. [10]
  Tingbo Wang , Yao Luo , Bingyan Hu , Ruiyuan Liu , Jing Miao , Huizhe Lu . Quantitative Computational Study on the Claisen Rearrangement Reaction of Allyl Phenyl Ethers: An Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(11): 278-285. doi: 10.12461/PKU.DXHX202403082
11. [11]
  Yiming Liang , Ziyan Pan , Kin Shing Chan . One Drink, Two Tears in the Central Nervous System: The Perils of Disulfiram-Like Reactions. University Chemistry, 2025, 40(4): 322-325. doi: 10.12461/PKU.DXHX202406016
12. [12]
  Xuyu WANG , Xinran XIE , Dengke CAO . Photoreaction characteristics and luminescence modulation in phosphine-anthracene-based Au(Ⅰ) and Ir(Ⅲ) complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1513-1522. doi: 10.11862/CJIC.20250113
13. [13]
  Jiageng Li , Putrama . 数值积分耦合非线性最小二乘法一步确定反应动力学参数. University Chemistry, 2025, 40(6): 364-370. doi: 10.12461/PKU.DXHX202407098
14. [14]
  Zhongyan Cao , Shengnan Jin , Yuxia Wang , Yiyi Chen , Xianqiang Kong , Yuanqing Xu . Advances in Highly Selective Reactions Involving Phenol Derivatives as Aryl Radical Precursors. University Chemistry, 2025, 40(4): 245-252. doi: 10.12461/PKU.DXHX202405186
15. [15]
  Nan Xiao , Fang Sun . 二芳基硫醚化合物的构建及应用. University Chemistry, 2025, 40(6): 360-363. doi: 10.12461/PKU.DXHX202407099
16. [16]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
17. [17]
  Wentao Lin , Wenfeng Wang , Yaofeng Yuan , Chunfa Xu . Concerted Nucleophilic Aromatic Substitution Reactions. University Chemistry, 2024, 39(6): 226-230. doi: 10.3866/PKU.DXHX202310095
18. [18]
  Zhi Chai , Huashan Huang , Xukai Shi , Yujing Lan , Zhentao Yuan , Hong Yan . Wittig反应的立体选择性. University Chemistry, 2025, 40(8): 192-201. doi: 10.12461/PKU.DXHX202410046
19. [19]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
20. [20]
  Yuting Zhang , Zhiqian Wang . Methods and Case Studies for In-Depth Learning of the Aldol Reaction Based on Its Reversible Nature. University Chemistry, 2024, 39(7): 377-380. doi: 10.3866/PKU.DXHX202311037

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(393)
HTML views(38)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return

FeCl3·6H2O-Mediated Deacetylation/Decarboxylation of α-Carbonyl-α-aceto/Carboxyl Cyclic Ketene Dithioacetals

Metrics

通讯作者: 陈斌, bchen63@163.com

FeCl₃·6H₂O-Mediated Deacetylation/Decarboxylation of α-Carbonyl-α-aceto/Carboxyl Cyclic Ketene Dithioacetals