Citation: Zhang Meiqi, Zhao Yanxia, He Shenggui. Reactions of Noble Metal Species with Methane in Gas-Phase[J]. Chemistry, ;2016, 79(5): 395-402. shu

Reactions of Noble Metal Species with Methane in Gas-Phase

1.
1. Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190;
2.
2. University of Chinese Academy of Sciences, Beijing 100049

Corresponding author: He Shenggui,
Received Date: 6 November 2015
Available Online: 19 November 2015
Fund Project:

Noble metals have been identified to exhibit excellent performance in methane chemistry. Gas phase study of chemical reactions between noble metal species and methane permits to uncover the active sites and elementary reaction mechanisms involved in condensed-phase catalytic reactions at a strictly molecular level. In this review, we summarize the recent progress in activation and transformation of methane by noble metal species including single atoms, atomic ions, cluster ions, hydrides, halides, oxides, metal-methyl complexes, and heteronuclear clusters. The mechanistic difference of methane activation by different noble metal systems is also discussed in detail.
- Noble Metals,
- Methane,
- Atomic clusters,
- Reaction mechanisms
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