Citation: Li Ping. Space Group Deduction of Hexagonal Vanadium Sulfide Crystal[J]. Chemistry, ;2016, 79(8): 775-783,774. shu

Space Group Deduction of Hexagonal Vanadium Sulfide Crystal

Li Ping

1.
College of Chemistry, Sichuan University, Chengdu 610061

Received Date: 3 December 2015
Available Online: 24 February 2016
Fund Project:

The space group deductions of crystals are the key link in the descriptions and expressions of crystal structures, and are the theoretical means as well for verifying the experimental structures. Because the descriptions involve mathematics methods, physics techniques, and graphics software usages, therefore, they are not only teaching emphases but also difficulties. Based on the parameters of crystal structure determinations of hexagonal vanadium sulfide, we can reproduce the crystal pattern in graphics software with self-compiling crystallographic code cryst 2015. In the point space and three-dimensional real vector space, the space group and the matrix representation group were obtained by expressing the translational and symmetrical operations with the linear mapping. The products of power of generators unambiguously derive the formation sequence of elements of space group and the crystallographic classification. This coherently deductive method with an example is advantageous for students to establish the crystallographic knowledge framework, especially is able to help abecedarians to comprehend the scientific ideological system of crystallography.
- Vanadium sulfide,
- Space group,
- Linear transformation matrix,
- Hexagonal system,
- Proper unit cell
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