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Citation: Li Yingjie, Liu Shuren, Gao Lidi, Lü Renjiang. Preparation and Application of Maleic Anhydride-β-cyclodextrin Monolithic Column for Capillary Electrochromatography[J]. Chemistry, ;2016, 79(8): 749-753. shu

Preparation and Application of Maleic Anhydride-β-cyclodextrin Monolithic Column for Capillary Electrochromatography

1.
College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006

Corresponding author: Gao Lidi,
Received Date: 10 November 2015
Available Online: 18 March 2016
Fund Project:

Maleic anhydride-β-cyclodextrin chiral monolithic capillary electrochromatography column was prepared by one-step reaction with maleic anhydride-β-cyclodextrin(MAH-β-CD), glycidyl methacrylate (GMA) and ethylene glycol dimethacrylate (EDMA) as functional monomers. Moreover, the preparation conditions of the monolithic column were also optimized. The structure and morphology of the monolithic column were characterized by IR and SEM. The column efficiency determined by using thiourea as the neutral marker was 99856 plates/m. The column was evaluated by arginine. The new monolithic column had good chiral recognition ability, better reproducibility and easy operation. In capillary electrochromatography mode, the Salbutamol enantiomers were separated by capillary electrochromatography-mass spectrometry (CEC-MS), and the resolution is 1.67.
- Monolithic column,
- Maleic anhydride-β-cyclodextrin,
- CEC-MS,
- Enantiomer separation
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