Citation:
Li Tiemei, Song Yuefei, Lv Xiangying, Fan Jing. Progress of Preparation and Applications of Ionic Liquid and Polymeric Ionic Liquid-Based Sorbent Coating in Solid-Phase Microextraction[J]. Chemistry,
;2016, 79(8): 723-730.
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Solid-phase microextraction (SPME) has been developed rapidly as a new sample pretreatment technique due to its simplicity, short duration, easy automation, and solvent-free properties. Coating is the core of SPME technique, which determines the selectivity and extraction capacity of analysis. Ionic liquids (ILs) and polymeric ionic liquids (PILs), which possess unique properties such as environment-friendliness, negligible vapor pressure, good thermal stability, design flexibility, high viscosity and so on, have been exploited as sorbent coatings in SPME for various analytes, exhibiting excellent extraction effect and unique selectivity. This paper comprehensively reviewed the progress of IL and PIL-based sorbent coatings in SPME in the following aspects, characteristics of preparation, coating morphology, selectivity, stability and coating lifetime and applications for the past few years. Then, the advantages and disadvantages of this technology were discussed. Finally, the improving direction of the preparation and applications of IL and PIL-based sorbent coatings in SPME were prospected.
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