Citation: Feng Xiaojuan, Shi Yanlong, Shao Qianfei, Jin Xiaoqing, Li Yongyan. Preparation and Supercapacitive Performance of Porous Crosslinked Mn²⁺-Doped Polyaniline/Reduced Graphene Oxide Composite[J]. Chemistry, ;2016, 79(9): 828-833,804. shu

Preparation and Supercapacitive Performance of Porous Crosslinked Mn²⁺-Doped Polyaniline/Reduced Graphene Oxide Composite

1.
College of Chemistry and Chemical Engineering, Key Laboratory of Hexi Corridor Resources Utilization of Gansu Universities, Hexi University, Zhangye 734000

Corresponding author: Feng Xiaojuan,
Received Date: 29 January 2016
Available Online: 20 April 2016
Fund Project:

The Mn²⁺ doped-polyaniline(PANI)/reduced graphene oxide (rGO) composite was successfully prepared via a simple in-situ chemical oxidative polymerization method.FT IR, XRD, SEM and electrochemical measurements were employed to investigate the structure, morphology and electrochemical capacitance performance of the composite. The results showed that the Mn²⁺ doped-polyaniline with nanorods structure was well distributed into the corrugated graphene layers, and the porous cross-linked structure was formed. The specific capacitance of as-prepared PANI/rGO compsite is 952 F/g under the current density of 2 A/g. After 1000 cycles, the capacitance value remains about 86.2% of that of initial cycle. Transition metal doping and rGO enhanced the electrochemical properties of the nanocomposites. The better specific capacitance and charge/discharge rates make them promising candidates as electrodes in supercapacitors.
- Transition metal,
- Doped-Polyaniline,
- Graphene,
- Electrochemical capacitance
1. [1]
  [1] P Simon, Y Gogotsi. Nat. Mater., 2008, 7:845~854.
2. [2]
  [2] L L Zhang, X S Zhao. Chem. Soc. Rev., 2009, 38:2520~2531.
3. [3]
  [3] 冯晓娟, 石彦龙, 蔺旺梅等. 化学通报, 2016,79(1):71~76.
4. [4]
  [4] X J Feng, Y L Shi, S P Jin. Appl. Surf.Sci., 2015,353:788~792.
5. [5]
  [5] 金玉红, 王莉, 尚玉明等. 化学通报, 2014, 77(11):1045~1053.
6. [6]
  [6] H L Wang, Q L Hao, X Wang. Nanoscale, 2010, 2:2164~2170.
7. [7]
  [7] A K Sarker, J D Hong. Lagmuir, 2012, 28:12637~12646.
8. [8]
  [8] L Li, H L Fei, Y Yang et al. ACS Appl. Mater. Interf., 2013, 5:6622~6627.
9. [9]
  [9] 方静, 崔沐, 张治安等. 功能材料, 2011, 42(1):171~174.
10. [10]
  [10] S Dhibar, C K Das. Ind. Eng. Chem. Res., 2014, 53:3495~3508.
11. [11]
  [11] W S Hummers, R E Offeman. J. Am. Chem. Soc., 1958, 80(6) 1339.
12. [12]
  [12] C H Kim, S Pyun, H C Shin. J. Electrochem. Soc., 2002, 149:A93~A98.
13. [13]
  [13] C M Wang, C Y Chen, Y Zeng. Spectrochim. Acta A, 2007, 66:37~41.
14. [14]
  [14] J Yan, T Wei, Z Fan. J. Power Sources, 2010, 195:3041~3045.
15. [15]
  [15] A Tawansi, A El-khodary, H M Zidan et al. Polym. Test., 2002, 21:381~387.
16. [16]
  [16] C C Hu, C C Wang. J Electrochem. Soc., 2003,150(8):A1079~A1084.
17. [17]
  [17] S Dhibar, P Bhattacharya, G Hatui et al. Ind. Eng. Chem. Res., 2014, 2:1114~1127.
18. [18]
  [18] W L Wu, Y F Li, L Q Yang et al. Electrochim. Acta, 2014,139:117~126.
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Supercapacitive Performance of Porous Crosslinked Mn2+-Doped Polyaniline/Reduced Graphene Oxide Composite

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通讯作者: 陈斌, bchen63@163.com

Preparation and Supercapacitive Performance of Porous Crosslinked Mn²⁺-Doped Polyaniline/Reduced Graphene Oxide Composite