Citation: Song Fengdan, Li Yuanjin, Yue Jiaqi, Qi Suitao, Yang Bolun. Preparation of Ni Nano Catalysts and the Activity for the Electrocatalytic Oxidation of Glucose[J]. Chemistry, ;2016, 79(9): 822-827. shu

Preparation of Ni Nano Catalysts and the Activity for the Electrocatalytic Oxidation of Glucose

1.
School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an 710049

Corresponding author: Qi Suitao,
Received Date: 25 January 2016
Available Online: 20 April 2016
Fund Project:

Ni/AC nano catalysts with different Ni loading on activated carbon(AC) were prepared by incipient wetness impregnation and temperature programmed reduction method. Their morphology and structure were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM) and X-ray photoelectron spectroscopy (XPS). Cyclic voltammetry was used to explore their activity for elctrocatalytic oxidation of glucose. The results showed that 20%Ni/AC/GC (Ni/AC nano catalyst was modified on a glassy carbon electrode) electrodes had a superior electrocatalytic activity for glucose oxidation. It brought a distinct and fast voltaic response in alkaline medium and the response current was significantly increased with the increase of glucose concentration. The linear response range of 20%Ni/AC/GCE was 0.2~6.5 mmol/L, the correlation coefficient was 0.999, the sensitivity was 13.15 μA/(mmol/L) and the lowest detectable limit was 35 μmol/L. It was found that the response current of 20%Ni/AC/GCE for glucose electrocatalytic oxidation could be able to reach 95% of the original current after three weeks when it was tested every three days, which indicates the Ni/AC/GCE electrode has a good stability.
- Ni/AC,
- Glucose,
- Electrocatalytic,
- Oxidation,
- Cyclic voltammetry
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沈阳化工大学材料科学与工程学院沈阳 110142